Abstract
We propose a method of measurement and quantitative estimation of dichroic ratios of submicron laminated Langmuir–Blodgett films by the IR spectra of multiple attenuated internal reflection. The method has been used in calculating the angles of orientation of molecular chains of stearic and palmitic acids in the process of their molecular deposition on an optical substrate. It has been found that in the process of structural self-organization of ensembles the degree of orientation of macromolecules is the higher, the greater the number of links entering into the aliphatic chain.
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REFERENCES
B. Ke, New Methods of Investigating Polymers [Russian translation], Moscow (1966).
L. M. Blinov, Usp. Fiz. Nauk, 155, 443-495 (1988).
A. V. Kir'yanov, I. A. Maslenitskii, V. V. Savranskii, V. D. Shigorin, and H. Lemmetiynen, Kvantovaya Elektron., 26, 85–89 (1999).
S. P. Palto, Stark Spectroscopy of Langmuir-Blodgett Films, Author's Abstract of Candidate Thesis (Physics and Math) [in Russian], Moscow (1988).
S. S. Gusev, Zh. Prikl. Spektrosk., 42, 866 (1985).
L. E. Starovoitov, S. S. Gusev, and N. I. Stas'kov, Poverkhnost'. Fiz., Khim., Mekh., 5, 89–93 (1989).
P. A. Cholett, and J. J. Messier, Thin Solid Films, 66, 13–19 (1980).
P. G. De Gennes, J. Phys. Lett., Ser. A, 47, 123–126 (1974).
M. R. Buhaenko, J. M. Goodwin, R. M. Richardson, and M. F. Daniel, Thin Solid Films, 134, 217–222 (1985).
P. A. Cholett, and J. J. Messier, Thin Solid Films, 99, 197–204 (1983).
N. Harruk, Internal Reflection Spectroscopy [Russian translation], Moscow (1970).
H. J. Harruk and F. K. du Pre, J. Appl. Opt., 5, 1739–1743 (1966).
W. N. Hansen, J. Soc. Am. Trans., 4, 263–267 (1965).
D. V. Van Krevelen, Properties and Chemical Structure of Polymers [Russian translation], Moscow (1976).
W. Muhch, U. Fringeli, and H. Gunthard, J. Spectrochim. Acta, 33A, 95–99 (1977).
I. M. Dechant, R. Danz, V. Kimmer, and R. Schmolke, Infrared Spectroscopy of Polymers [Russian translation], Moscow (1976).
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Gusev, S.S., Starovoitov, L.E. & Plisko, A.I. IR Dichroism of Langmuir–Blodgett Films Based on Fatty Acids. Journal of Applied Spectroscopy 67, 1058–1062 (2000). https://doi.org/10.1023/A:1004145010162
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DOI: https://doi.org/10.1023/A:1004145010162