Abstract
An experimental study of electroplated thin films of bismuth telluride, R3m crystal structure, shows that fibre textures are observed during the growth of the layers. Several orientations 〈00.1〉, 〈10.10〉, 〈11.0〉, 〈10.4〉, 〈10.8〉, 〈01.5〉 and 〈10.0〉 are developed during the deposition process, then reach a final orientation. Hartman's theory of crystal growth based on the periodic bond chain (PBC) in a crystal lattice is usually applied. This explains the equilibrium shape of a crystal defined by F faces and the faces observed during the growth (S and K faces). It also successfully predicts the orientations observed in bismuth telluride from the beginning to the end of the layer deposition. The theory may also be applied to other deposition processes.
Similar content being viewed by others
References
D.B. Knorr and D.P. Tracy, International Conferences on Texture of Material, ICOTOM 10 (1993) 1443-8.
I. Handreg and P. Klimanek, Materi. Sci. Forum 157-162 (1994) 1405-10.
H. Chaouni, PhD thesis, University of Metz (1995).
P. Hartman, ‘Crystal Growth’ (Elsevier, 1973), p.376.
P. Hartman, J. Cryst. Growth 63 (1983) 261-4.
J.H. Horst and R.M. Geertman, Acta Cryst. Section A vol A52 Supplement Pp C516 Iucr XVII Congress, Seattle (1996).
L.G. Schulz, J Appl. Phys. 20 (1949) 1030-33.
M.J. Bunge, ‘Mathematische Methoder der Texturanalyse’ (Academic-Verlag, Berlin, 1969).
J.J. Heizmann, C. Laruelle and A. Vadon, J. Appl. Crystallogr. 19 (1986) 467-72.
P. Magri, C. Boulanger and J.M. Lecuire, J. Mater. Chem. 6 (1996) 773-9.
J.P. Fleurial, PhD thesis á l'I. N.P.L., University of Nancy (1988).
H. Chaouni, P. Magri, J. Bessières, C. Boulanger and J.J Heizmann, Mater. Sci. Forum 157-162 (1994) 1371-77.
L. Kullmann, Phys. Status Solidi B (1984) 125-31.
J.R. Weise and L. Muldawer, J. Phy. Chem Solids. 15 (1960) 13-16.
S. Toschev, ‘Crystal Growth’ (Elsevier, 1973), p. 328.
P. Bennena, ‘Crystal Growth’ (Elsevier, 1973), p. 342.
H. Chaouni, J. Bessières and J.J. Heizmann, International Conferences in Texture of Material, ICOTOM 11 2 (1996) 1118-25.
I. Handreg and P. Klimanek, International Conferences on Texture of Material, ICOTOM 10 (1993) 1405-10.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Chaouni, H., Bessières, J., Modaressi, A. et al. Texture prediction of Bi2Te3 electroplated layers using Hartman's theory of crystal growth. Journal of Applied Electrochemistry 30, 419–427 (2000). https://doi.org/10.1023/A:1003790504717
Issue Date:
DOI: https://doi.org/10.1023/A:1003790504717