Skip to main content
Log in

Evaluation of the surface roughness of microporous Ni–Zn–P electrodes by in situ methods

  • Published:
Journal of Applied Electrochemistry Aims and scope Submit manuscript

Abstract

The surface roughness of porous Ni–Zn–P electrodes was studied in 1 M NaOH using in situ electrochemical techniques: ratio of the polarization current densities, electrochemical impedance spectroscopy, cyclic voltammetry, coulometric oxidation of the surface, and a new technique of a CO molecular probe. The obtained surface roughness was about 5.5 × 103. Good agreement was observed between the results obtained by all these techniques.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. S. Trasatti and O.A. Petrii, Pure Appl. Chem. 63 (1991) 711.

    Google Scholar 

  2. A.T. Kuhn, In: A.T. Kuhn (ed.) Techniques in Electrochemistry, Corrosion and Metal Finishing, J. Wiley & Sons, Chichester, (1987) p. 95.

    Google Scholar 

  3. A. Lasia, Current Topics Electrochem. 2 (1993) 239.

    Google Scholar 

  4. P. Gu, L. Bai, R. Brousseau and B.E. Conway, Electochim. Acta. 37 (1992) 2145.

    Google Scholar 

  5. L. Bai, L. Gao and B.E. Conway, J. Chem. Soc. Faraday Trans. 89 (1993) 235.

    Google Scholar 

  6. R. SÏ impraga, G. Tremiliosi-Filho, S.Y. Qian and B.E. Conway, J. Electroanal. Chem. 424 (1997) 141.

    Google Scholar 

  7. N.A. Assunção, M.J. de Giz, G. Tremiliosi-Filho and E.R. Gonzalez, J. Electrochem. Soc. 144 (1997) 2794.

    Google Scholar 

  8. S. Rauch and H. Wendt, J. Electrochem. Soc. 143 (1996) 2852.

    Google Scholar 

  9. S.A.S. Machado, J. Tiengo, P. de Lima Neto and L.A. Avaca, Electrochim. Acta 39 (1994) 1757.

    Google Scholar 

  10. S.A.S. Machado, J. Tiengo, P. de Lima Neto and L.A. Avaca, J. Appl. Electrochem. 26 (1996) 431.

    Google Scholar 

  11. C.A. Marozzi and A.C. Chialvo, Electrochim. Acta 41 (1996) 2351 and 2361.

    Google Scholar 

  12. T. Biegler, D.A.J. Rand and R. Woods, J. Electroanal. Chem. 29 (1971) 269.

    Google Scholar 

  13. J.C.K. Ho and D.L. Piron, J. Electrochem. Soc. 142 (1995) 1144.

    Google Scholar 

  14. A. Lasia, Polish J. Chem. 69 (1995) 639.

    Google Scholar 

  15. K. Wang, G.S. Chottiner and D.A. Scherson, J. Phys. Chem. 96 (1992) 6742.

    Google Scholar 

  16. M. Zhao, K. Wang and D.A. Scherson, J. Phys. Chem. 97 (1993) 4488.

    Google Scholar 

  17. C.F. Zinola, E.J. Vasini, U. MuÈ ller, H. Baltruschat and A.J. Arvia, J. Electroanal. Chem. 415 (1996) 165.

    Google Scholar 

  18. A. Cuesta and C. Gutie rrez, J. Phys. Chem. 100 (1996) 12600.

    Google Scholar 

  19. R. Karimi Shervedani and A. Lasia, J. Electrochem. Soc. 144 (1997) 2652.

    Google Scholar 

  20. R. Karimi Shervedani and A. Lasia, J. Electrochem. Soc. 144 (1997) 511.

    Google Scholar 

  21. A. Lasia and A. Rami, J. Electroanal. Chem. 294 (1990) 123.

    Google Scholar 

  22. P. Los, A. Lasia, H. Me nard and L. Brossard, J. Electroanal. Chem. 360 (1993) 101.

    Google Scholar 

  23. G.J. Brug, A.L.G. van den Eeden, M. Sluyters-Rehbach and J.H. Sluyters, J. Electroanal. Chem. 176 (1984) 275.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Shervedani, R.K., Lasia, A. Evaluation of the surface roughness of microporous Ni–Zn–P electrodes by in situ methods. Journal of Applied Electrochemistry 29, 979–986 (1999). https://doi.org/10.1023/A:1003577631897

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1003577631897

Navigation