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Triterpenoid Glycosides of Fatsia japonica. II. Isolation and Structure of Glycosides from the Leaves

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Abstract

The previously known triterpenoid 3-O-α-L-arabinopyranosides of oleanolic and echinocystic acids and hederagenin, 3-O-β-D-glucopyranosyl-(1→2)-O-α-L-arabinopyranosides of oleanolic acid and hederagenin, in addition to 28-O-α-L-rhamnopyranosyl-(1→4)-O-β-D-glucopyranosyl-(1→6)-O-β-D-glucopyranosyl ethers of the 3-O-α-L-arabinopyranoside of hederagenin, and 3-O-β-D-glucopyranosyl-(1→2)-O-α-L-arabinopyranosides of oleanolic acid and hederagenin, respectively, are isolated from leaves ofFatsia japonica(Araliaceae). The structures of the glycosides are confirmed by chemical methods and 13 C NMR spectroscopy

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Authors and Affiliations

  1. V. I. Vernadskii Tavricheskii National University, 95007, Simferopol', ul. Yaltinskaya, 4

    V. I. Grishkovets, E. A. Sobolev & V. Ya. Chirva

  2. N. D. Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, 117913, Moscow, B-334, Leninskii prospekt, 47

    A. S. Shashkov

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  1. V. I. Grishkovets
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  2. E. A. Sobolev
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  3. A. S. Shashkov
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  4. V. Ya. Chirva
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Grishkovets, V.I., Sobolev, E.A., Shashkov, A.S. et al. Triterpenoid Glycosides of Fatsia japonica. II. Isolation and Structure of Glycosides from the Leaves. Chemistry of Natural Compounds 36, 501–505 (2000). https://doi.org/10.1023/A:1002891507725

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  • DOI: https://doi.org/10.1023/A:1002891507725

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