Abstract
The necessary and sufficient conditions to which the model kinetic equations and the caloric equation of state should be subject for consistency with the second principle of thermodynamics are given. A simple model whose accuracy compares with that of the models with detailed kinetics and a highly accurate description of the constants of equilibrium of the reactions and the internal energies of the components of a mixture is proposed.
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REFERENCES
Yu. A. Nikolaev, "Kinetic model for chemical reactions at high temperatures," Fiz. Goreniya Vzryva, 14, No. 4, 73-76 (1978).
Yu. A. Nikolaev and P. A. Fomin, " Calculation of the equilibrium ows of chemically reacting gases," Fiz. Goreniya Vzryva, 18, No. 1, 66-72 (1982).
Yu. A. Nikolaev and D. V. Zak, "Consistency of the models of chemical reactions in gases with the second principle of thermodynamics," Fiz. Goreniya Vzryva, 24, No. 4, 87-90 (1988).
R. A. Strehlow, R. E. Maurer, and S. Rajan, "Transverse waves in detonation. I. Spacings in the hydrogen―oxygen system," AIAA J., 7, No. 2, 323-328 (1969).
W. C. Gardiner, Jr. (ed.), Combustion Chemistry, Springer-Verlag, New York―Berlin―Heidelberg― Tokyo (1984).
E. S. Shchetinkov, Physics of Gas Combustion [in Russian], Nauka, Moscow (1965).
V. P. Glushko (ed.), Thermodynamic Properties of Individual Substances [in Russian], Vol. 2, Izd. Akad. Nauk SSSR, Moscow (1962).
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Nikolaev, Y.A. Approximate Modeling, a Kinetic Model, and a Caloric Equation of State for Chemically Reacting Gas Mixtures at High Temperatures. Combustion, Explosion, and Shock Waves 37, 4–12 (2001). https://doi.org/10.1023/A:1002852205753
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DOI: https://doi.org/10.1023/A:1002852205753