Abstract
N-Substituted 2-iminocoumarins are formed on reacting 2-iminocoumarin-3-carboxamide with anthranilic acid, methyl anthranilate, anthranilamide, and anthranilonotrile. Depending on the reaction conditions these recyclize into the corresponding 3-substituted coumarins or are hydrolyzed to coumarin-3-carboxamide. An alternative synthesis of some of the compounds has been effected.
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Kovalenko, S.N., Bylov, I.E., Belokon', Y.V. et al. Action of Nucleophilic Reagents. 5. Interaction of 2-Iminocoumarin-3-carboxamide with Anthranilic Acid and its Derivatives. Chemistry of Heterocyclic Compounds 36, 1026–1031 (2000). https://doi.org/10.1023/A:1002773613250
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DOI: https://doi.org/10.1023/A:1002773613250