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Modified Glassy-Carbon Electrodes for the Flow-Injection Determination of Inorganic Tin Species by Stripping Voltammetry

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Abstract

The behavior of tin(II, IV) chloride species on an unmodified glassy-carbon electrode, and on or at film electrodes obtained by the electrooxidative modification of a glassy-carbon surface, in solutions of some polyphenols and other hydroxyl-containing aromatic compounds (salicylic acid and morin) was studied by cyclic voltammetry. The optimum conditions were found for the potentiostatic formation of films reproducible in thickness in the cyclic hydrodynamic mode. A comparison of the results of the studies demonstrated the effect of hydrophobic film nature on the redox processes observed in Sn(II, IV) and Pb(II) chloride solutions at different pHs. All the electrodes proposed preconcentrated tin(II) from flow solutions without applying a polarization voltage. The interfering effect of lead(II) was minimized by selecting an appropriate accumulation medium. The modified electrodes prepared by the electrooxidation of pyrogallol and morin were used for the flow-injection determination of trace amounts of Sn(II) in the presence of Sn(IV) and Pb(II) and for the determination of the total inorganic tin in model solutions by anodic stripping voltammetry.

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  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    L. K. Shpigun & V. K. Lunina

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  1. L. K. Shpigun
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  2. V. K. Lunina
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Shpigun, L.K., Lunina, V.K. Modified Glassy-Carbon Electrodes for the Flow-Injection Determination of Inorganic Tin Species by Stripping Voltammetry. Journal of Analytical Chemistry 58, 1078–1084 (2003). https://doi.org/10.1023/A:1027341624232

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