Advertisement

Kinetics and Catalysis

, Volume 41, Issue 6, pp 753–755 | Cite as

Methanol Decomposition in a Water–Methanol Equimolar Mixture on a Nickel-Promoted Copper–Zinc–Cement Catalyst

  • S. N. Antonyuk
  • A. L. Lapidus
  • V. B. Kazanskii
  • V. I. Yakerson
  • A. A. Khanumyan
  • E. Z. Golosman
  • A. I. Nechugovskii
  • O. Yu. Pesin
Article

Abstract

Methanol decomposition in a water–methanol equimolar mixture is studied in the presence of a nickel-promoted copper–zinc–cement catalyst. Methanol decomposition at 200–300°C on the oxide and reduced forms of the catalyst yields a gas with an H2/CO ratio close to two. The use of an equimolar CH3OH–H2O mixture under analogous conditions enables obtaining gaseous products with a hydrogen concentration up to 75 vol %.

Keywords

Oxide Hydrogen Copper Methanol Zinc 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

REFERENCES

  1. 1.
    Smal', F.V. and Aksenov, E.E., Perspektivnye topliva dlya avtomobilei (Promising Fuel for Cars), Moscow: Transport, 1979, p. 41.Google Scholar
  2. 2.
    Kataliz v C1-khimii (Catalysis in C1 Chemistry), Kaim, W., Ed., Leningrad: Khimiya, 1987, p. 97.Google Scholar
  3. 3.
    Janda, Z., Hutnik, 1987, no. 8, p. 317.Google Scholar
  4. 4.
    Bond, G.C., Catalysis by Metals, New York: Academic, 1962.Google Scholar
  5. 5.
    Amphlett, J.C., Evans, M.J., Jones, R.A., et al., Can. J. Chem. Eng., 1981, vol. 59, p. 720.Google Scholar
  6. 6.
    Tada, A., Yoshino, T., and Iton, H., Chem. Lett., 1987, vol. 2, p. 419.Google Scholar
  7. 7.
    Gel'man, V.N., Karvovskaya, A.A., Golosman, E.Z., and Nechugovskii, A.I., Khim. Promst., 1994, no. 12, p. 22.Google Scholar
  8. 8.
    Ismailov, T.S., Galsekov, T.Sh., and Ismailova, E.Sh., Zh. Obshch. Khim., 1974, vol. 44, no. 12, p. 2738.Google Scholar

Copyright information

© MAIK “Nauka/Interperiodica” 2000

Authors and Affiliations

  • S. N. Antonyuk
    • 1
  • A. L. Lapidus
    • 2
  • V. B. Kazanskii
    • 2
  • V. I. Yakerson
    • 2
  • A. A. Khanumyan
    • 1
  • E. Z. Golosman
    • 3
  • A. I. Nechugovskii
    • 3
  • O. Yu. Pesin
    • 1
  1. 1.Lomonosov State Academy of Fine Chemical TechnologyMoscowRussia
  2. 2.Zelinskii Institute of Organic ChemistryRussian Academy of SciencesMoscowRussia
  3. 3.Novomoskovsk Institute of Nitrogen IndustryNovomoskovskRussia

Personalised recommendations