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Kinetics of Ketone Oxidation by Ozone in Water Solutions

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Abstract

The spectrophotometric monitoring of ozone consumption in a liquid phase is used to study the kinetics of cyclopentanone and methyl butyl ketone oxidation. The rate of ozone reaction with ketones (RH) at 303–344 K in acidic (HClO4) aqueous solutions is described by the equation w = k 1[RH][O3] + k En[RH][HClO4], where k 1 is the rate constant for the reaction of ozone with RH and k En is the rate constant for the enolization of RH. The kinetic parameters of the process are found.

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  1. Bashkortostan State University, Ufa, 450007, Bashkortostan, Russia

    Yu. S. Zimin, N. V. Trukhanova, A. Ya. Gerchikov, E. M. Butasova & E. A. Zubairova

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  1. Yu. S. Zimin
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  2. N. V. Trukhanova
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  3. A. Ya. Gerchikov
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  4. E. M. Butasova
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  5. E. A. Zubairova
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Zimin, Y.S., Trukhanova, N.V., Gerchikov, A.Y. et al. Kinetics of Ketone Oxidation by Ozone in Water Solutions. Kinetics and Catalysis 41, 745–748 (2000). https://doi.org/10.1023/A:1026656616132

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  • DOI: https://doi.org/10.1023/A:1026656616132

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