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The D/H Ratio in Chondrites

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Abstract

The statistical distribution of all available published D/H ratios of carbonaceous chondrites is presented. The possible interpretations of this distribution are reviewed at the global scale of the solar system planetary objects and at the scale defined by the carbonaceous meteorites. New issues concerning the chemical origin of the deuterium enrichment in solar system water and organic molecules are put into light by this exercise. This distribution is a robust constraint on the origin of water on Earth.

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References

  • Aléon, J., Engrand, C., Robert, F., and Chaussidon, M.: 2001, 'Clues to the Origin of Interplanetary Dust Particles from the Isotopic Study of their Hydrogen-bearing Phases', Geochim. Cosmochim. Acta 65, 4399–4412.

    Article  ADS  Google Scholar 

  • André, P., and Montmerle, T.: 1994, 'From T Tauri Stars to Protostars: Circumstellar Material and Young Stellar Objects in the p-Ophiuchi Cloud', Astrophys. J. 420, 837–862.

    Article  ADS  Google Scholar 

  • Balsiger, H., Altwegg, K., and Geiss, J.: 1995, 'D/H and 18O/16O Ratio in the Hydronium Ion and in Neutral Water from in Situ Ion Measurements in Comet P/Halley', J. Geophys. Res. 100, 5827–5834.

    Article  ADS  Google Scholar 

  • Becker, R.H., and Epstein, S.: 1982, 'Carbon, Hydrogen, and Nitrogen Isotopes in Solvent-extractable Organic Matter from Carbonaceous Chondrites', Geochim. Cosmochim. Acta 46, 97–103.

    Article  ADS  Google Scholar 

  • Boato, G.: 1954, 'The Isotopic Composition of Hydrogen and Carbon in the Carbonaceous Chondrites', Geochim. Cosmochim. Acta 6, 209–220.

    Article  ADS  Google Scholar 

  • Bockelée-Morvan, D., Gautier, D., Lis, D.C., Young, K., Keene, J., Phillips, T., Owen, T., Crovisier, J., Goldsmith, P.F., Bergin, E.A., Despois, D., and Wootten, A.: 1998, 'Deuterated Water in Comet C/1996 B2 (Hyakutake) and its Implications for the Origin of Comets', Icarus 133, 147–162.

    Article  ADS  Google Scholar 

  • Brown, P.D., and Millar, T.J.: 1989, 'Models of the Gaz-grain Interaction-Deuterium Chemistry', Mon. Not. Roy. Astron. Soc. 237, 661–671.

    ADS  Google Scholar 

  • Brown, R.D., and Rice, E.: 1981, 'Interstellar Deuterium Chemistry', Phil. Trans. Roy. Soc. London A303, 523–533.

    ADS  Google Scholar 

  • Bunch, T.E., and Chang, S.: 1980, 'Carbonaceous Chondrite: II. Carbonaceous Chondrites Phyllosilicates and Light Element Geochemistry as Indicators of Parent Body Processes and Surface Conditions', Geochim. Cosmochim. Acta 44, 1543–1577.

    Article  ADS  Google Scholar 

  • Cassen, P.: 1994, 'Utilitarian Models of the Solar Nebula', Icarus 112, 405–429.

    Article  ADS  Google Scholar 

  • Chiang, E.I., Joung, M.K., Creech-Eakman, M.J., Qi, C., Kessler, J.E., Blake, G.A., and van Dishoeck, E.F.: 2001, 'Spectral Energy Distributions of Passive T Tauri and Herbig Ae Disks: Grain Mineralogy, Parameter Dependences and Comparison with Infrared Space Observatory LWS Observations', Astrophys. J. 547, 1077–1089.

    Article  ADS  Google Scholar 

  • Dauphas, N., Robert, F., and Marty, B.: 2000, 'The Late Asteroidal and Cometary Bombardment of Earth as Recorded in Water Deuterium to Protium Ratio', Icarus 148, 508–512.

    Article  ADS  Google Scholar 

  • Deloule, E., and Robert, F.: 1995, 'Interstellar Water in Meteorites?', Geochim. Cosmochim. Acta 59, 4695–4706.

    Article  ADS  Google Scholar 

  • Deloule, E., Doukhan, J.-C., and Robert, F.: 1998, 'Interstellar Hydroxyle in Meteorite Chondrules: Implications for the Origin of Water in the Inner Solar System', Geochim. Cosmochim. Acta 62, 3367–3378.

    Article  ADS  Google Scholar 

  • Drake, M.J., and Righter, K.: 2002, 'Determining the Composition of the Earth', Nature 416, 39–44.

    Article  ADS  Google Scholar 

  • Drouart, A., Dubrulle, B., Gautier, D., and Robert, F.: 1999, 'Structure and Transport in the Solar Nebula from Constraints on Deuterium Enrichment and Giant Planet Formation', Icarus 140, 129–155.

    Article  ADS  Google Scholar 

  • Dubrulle, B.: 1992, 'A Turbulent Closure Model for Thin Accretion Disks', Astron. Astrophys. 266, 592–604.

    ADS  Google Scholar 

  • Eberhardt, P., Dolder, U., Schulte, W., Krankowsky, D., Lammerzahl, P., Hoffmann, J.H., Hodges, R.R., Berthelier, J.J., and Illiano, J.M.: 1987, 'The D/H Ratio in Water from Comet p/Halley', Astron. Astrophys. 187, 435–437.

    ADS  Google Scholar 

  • Eiler, J.M., and Kitchen, N.: 2002a, 'Hydrogen-isotope Geochemistry of the CM Chondrites', Abstract presented at the 2002 Goldschmidt Conf. in Davos.

  • Eiler, J.M., and Kitchen, N.: 2002b, 'Hydrogen Isotope Evidence for the Origin and Evolution of the CM Carbonaceous Chondrites', Geochim. Comochim. Acta, in preparation.

  • Encrenaz, T., and Owen, T.: 2003, 'Element Abundances and Isotope Ratios in the Giant Planets and Titan', Space Sci. Rev., this volume.

  • Engrand, C., Deloule, E., Robert, F., Maurette M., and Kurat, G.: 1999, 'Extraterrestrial Water in Micrometeorites and Cosmic Spherules from Antarctica: An Ion Microprobe Study', Met. Planet. Sci. 34, 773–786.

    ADS  Google Scholar 

  • Epstein, S., Krishnamurty, R.V., Cronin, J.R., Pizzarello, S., and Yuen, G.U.: 1987, 'Unusual Stable Isotope Ratios in Amino Acids and Carboxylic Acid Extracts from the Murchison Meteorite', Nature 326, 477–479.

    Article  ADS  Google Scholar 

  • Geiss, J., and Gloecker, G.: 1998, 'Abundances of Deuterium and Helium in the Protosolar Cloud', Space Sci. Rev. 84, 239–250.

    Article  ADS  Google Scholar 

  • Gensheimer, P.D., Mauersberger, R., and Wilson, T.L.: 1996, 'Water in Galactic Hot Cores', Astron. Astrophys. 314, 281–294.

    ADS  Google Scholar 

  • Glassgold, A., Feigelson, E.D., and Montmerle, T.: 2000, 'Effects on Energetic Radiation in Young Stellar Objects', in V. Mannings, A.P. Boss, and S.S. Russel (eds.), Protostars and Planets IV, University of Arizona Press, Tucson, pp. 429–455.

    Google Scholar 

  • Guélin, M., Langer, W.D., and Wilson, R.W.: 1982, 'The State of Ionization in Dense Molecular Clouds', Astron. Astrophys. 107, 107–127.

    ADS  Google Scholar 

  • Halbout, J., Robert, F., and Javoy, M.: 1990, 'Hydrogen and Oxygen Isotope Compositions in Kerogens from the Orgueil Meteorite: Clues to Solar Origin', Geochim. Cosmochim. Acta 54, 1453–1462.

    Article  ADS  Google Scholar 

  • Hersant, F., Gautier, D., Huré, J.-M.: 2001, 'A Two-dimensional Model for the Primordial Nebula Constrained by D/H Measurements in the Solar System: Implications for the Formation of Giant Planets', Astrophys. J. 554, 391–407.

    Article  ADS  Google Scholar 

  • Jacq, T., Walmzey, C.M., Henkel, C., Baudry, R., Mauersberger, R., and Jewell, P.R.: 1990, 'Deuterated Water and Ammonia in Hot Cores', Astron. Astrophys 228, 447–458.

    ADS  Google Scholar 

  • Kerridge, J.F.: 1985, 'Carbon, Hydrogen, and Nitrogen in Carbonaceous Meteorites: Abundances and Isotopic Compositions in Bulk Samples', Geochim. Cosmochim. Acta 49, 1707–1714.

    Article  ADS  Google Scholar 

  • Kerridge, J.F., Chang, S., and Shipp, R.: 1987, 'Isotope Characterisation of Kerogen-like Material in Murchison Carbonaceous Chondrite', Geochim. Cosmochim. Acta 51, 2527–2540.

    Article  ADS  Google Scholar 

  • Kolodny, Y., Kerridge, J.F., and Kaplan, I.R.: 1980, 'Deuterium in Carbonaceous Chondrites', Earth Planet. Sci. Lett. 46, 149–158.

    Article  ADS  Google Scholar 

  • Krishnamurthy, R.V., Epstein, S., Cronin, J.R., Pizzarello, S., and Yuen, G.U.: 1992, 'Isotopic and Molecular Analyses of Hydrocarbons and Monocarboxylic Acids of the Murchison Meteorite', Geochim. Cosmochim. Acta 56, 4045–4058.

    Article  ADS  Google Scholar 

  • Lécluse, C., and Robert, F.: 1994, 'Hydrogen Isotope Exchange Rates: Origin of Water in the Inner Solar System', Geochim. Cosmochim. Acta 58, 2297–2939.

    Google Scholar 

  • Lécuyer, C., Gillet, P., and Robert, F.: 1998, 'The Hydrogen Isotope Composition of Sea Water and the Global Water Cycle', Chem. Geology 145, 249–261.

    Article  Google Scholar 

  • Lellouch, E., Bézard, B., Feuchtgruber, T., Encrenaz, T., and de Graauw, T.: 2001, 'The Deuterium Abundance in Jupiter and Saturn from ISO-SWS Observations', Astron. Astrophys. 370, 610–622.

    Article  ADS  Google Scholar 

  • Linsky, J.L., Brown, A., Gayley, K., Diplas, A., Savage, B.D., Landsman, T.R., Shore, S.N., and Heap, S.R.: 1993, 'High-Resolution Spectrograph Observations of the Local Interstellar Medium and the D/H Ratio along the Line of Sight toward Capella', Astrophys. J. 402, 694–709.

    Article  ADS  Google Scholar 

  • Mahaffy, P.R., Donahue, T.M., Atreya, S.K., Owen, T.C., and Niemann, H.B.: 1998, 'Galileo Probe Measurements of D/H and 3He/4 He in Jupiter's Atmosphère', Space Sci. Rev. 84, 251–263.

    Article  ADS  Google Scholar 

  • McCullough, P.R.: 1992, 'The Interstellar Deuterium to Hydrogen Ratio: A Reevaluation of Lyman Absorbtion Line Measurements', Astrophys. J. 390, 213–225.

    Article  ADS  Google Scholar 

  • McNaughton, N.J., Borthwicks, S., Fallick, A.K., and Pillinger, C.T.: 1981, 'D/H Ratio in Unequilibrated Ordinary Chondrites', Nature 294, 639–641.

    Article  ADS  Google Scholar 

  • McNaughton, N.J., Fallick, A.E., and Pillinger, C.T.: 1982, 'Deuterium Enrichments in Type 3 Ordinary Chondrites', J. Geophys. Res. 87, 294–302.

    ADS  Google Scholar 

  • Meier, R., Owen, T.C., Matthews, H.E., Bockelée-Morvan, D.K., Biver, N., Crovisier, J., and Gautier, D.: 1998a, 'A Determination of the HDO/H2O Ratio in Comet C/1995 O1 (Hale-Bopp)', Science 279, 842–844.

    Article  ADS  Google Scholar 

  • Meier, R., Owen, T.C., Matthews, H.E., Bockelée-Morvan, D., Biver, N., Crovisier, J., and Gautier, D.: 1998b, 'A Determination of the HDO/H2O Ratio in Comet C/1995 O1 (Hale-Bopp)', Science 279, 842–844.

    Article  ADS  Google Scholar 

  • Messenger, S., Stadermann, F.J., Floss, C., Nittler, L.R., and Mukhopadyay, S.: 2003, 'Isotopic Signatures of Presolar Materials in Interplanetary Dust', Space Sci. Rev., this volume.

  • Millar, T.J., Bennett, A., and Herbst, E.: 1989, 'Deuterium Fractionation in Dense Interstellar Clouds', Astrophys. J. 340, 906–920.

    Article  ADS  Google Scholar 

  • Millar, T.J.: 2002, Proc. Meudon Symposium 2001: Deuterium in the Universe, personal communication and Planet. Space Sci., in press.

  • Morbidelli, A., Chambers, J., Lunine, J., Petit, J.M., Robert, F., and Valsecchi, G.B.: 2000, 'Source Regions and Timescales for the Delivery of Water on Earth', Met. Planet. Sci. 35, 1309–1320.

    ADS  Google Scholar 

  • Mousis, O., Gautier, D., Bockelée-Morvan, D., Robert, F., Dubrulle, B., and Drouart, A.: 2000, 'Constraints on the Formation of Comets from D/H Ratios Measured in H2O and HCN', Icarus 148, 513–525.

    Article  ADS  Google Scholar 

  • Pearson, V.K., Sephton, M.A., Gilmour, I., and Franchi, I.A.: 2001, 'Hydrogen Isotopic Composition of the Tagish Lake Meteorite: Comparison with other Carbonaceous Chondrites', Lunar Planet. Sci. XXXII, abstract # 1861.

  • Pizzarello, S., Krishnamurthy, R.V., Epstein, S., and Cronin, J.R.: 1991, 'Isotopic Analysis of Amino Acids from the Murchison Meteorite', Geochim. Cosmochim. Acta 55, 905–910.

    Article  ADS  Google Scholar 

  • Robert, F.: 2001, 'The Origin of Water on Earth', Science 293, 1056–1058.

    Article  Google Scholar 

  • Robert, F.: 2002, 'Water and Organic Matter in the Solar System as a Record of an Early Irradiation of the Protosolar Nebula', Proc. Meudon Symposium 2001: Deuterium in the Universe, Planet. Space Sci., in press.

  • Robert, F., and Epstein, S.: 1982, 'The Concentration of Isotopic Compositions of Hydrogen, Carbon, and Nitrogen in Carbonaceous Chondrites', Geochim. Cosmochim. Acta 16, 81–95.

    Article  ADS  Google Scholar 

  • Robert, F., and Deloule, E.: 2002, 'Using the D/H Ratio to Estimate the Terrestrial Water Contamination in Chondrites', Lunar Planet. Sci. Conf. XXXIII, 1299–1300 (pdf file).

    ADS  Google Scholar 

  • Robert, F., Merlivat, L., and Javoy, M.: 1979, 'Deuterium Concentration in the Early Solar System: A Hydrogen and Oxygen Isotopic Study', Nature 282, 785–789.

    Article  ADS  Google Scholar 

  • Robert, F.M., Javoy, J., Halbout, B., Dimon, B., and Merlivat, L.: 1987a, 'Hydrogen Isotopes Abundances in the Solar System, Part I: Unequilibrated Chondrites', Geochim. Cosmochim. Acta 51, 1787–1806.

    Article  ADS  Google Scholar 

  • Robert, F.M., Javoy, J., Halbout, B., Dimon, B., and Merlivat, L.: 1987b, 'Hydrogen Isotope Abundances in the Solar System, Part II: Meteorites with Terrestrial Like D/H Ratios', Geochim. Cosmochim. Acta 51, 1807–1822.

    Article  ADS  Google Scholar 

  • Robert, F., Gautier, D., and Dubrulle, B.: 2000, 'The Solar System D/H Ratio: Observations and Theories', in W. Benz, R. Kallenbach, and G.W. Lugmair (eds.), From Dust to Terrestrial Planets, Kluwer Acadmic Publishers, Dordrecht, Space Sci. Rev. 92, 201–224.

    Google Scholar 

  • Rodgers, S.D., and Millar, T.J.: 1996, 'The Chemistry of Deuterium in Hot Molecular Cores', Month. Not. Roy. Astron. Soc. 280, 1046–1054.

    ADS  Google Scholar 

  • Sandford, S.A., Bernstein, M.P., and Dworkin, J.P.: 2001, 'Assessment of the Interstellar Processes Leading to Deuterium Enrichment in Meteoritic Organics', Met. Planet. Sci. 36, 1117–1133.

    Article  ADS  Google Scholar 

  • Sears, D.W.G., Morse, A.D., Hutchison, R., Guimon, K.R., Jie, L., Alexander, C.M.O'D., Benoit, P.H., Wright, I., Pillinger, C., Xie, T., and Lipschutz, M.E.: 1995, 'Metamorphism and Aqueous Alteration in Low Petrographic Type Ordinary Chondrites', Meteoritics 30, 169–181.

    ADS  Google Scholar 

  • Vokrouhlicky, D., and Farinella, P.: 2000, 'Efficient Delivery of Meteorites to the Earth from a Wide Range of Asteroid Parent Bodies', Nature 407, 606–608.

    Article  ADS  Google Scholar 

  • Willacy, K., and Millar, T.J.: 1998, 'Adsorption Processes and the Deuterium Fractionation in Molecular Clouds', Month. Not. Roy. Astron. Soc. 228, 562–568.

    Article  ADS  Google Scholar 

  • Yang, J., and Epstein, S.: 1983, 'Interstellar Organic Matter in Meteorites', Geochim. Cosmochim. Acta 47, 2199–2216.

    Article  ADS  Google Scholar 

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Robert, F. The D/H Ratio in Chondrites. Space Science Reviews 106, 87–101 (2003). https://doi.org/10.1023/A:1024629402715

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