Abstract
The statistical distribution of all available published D/H ratios of carbonaceous chondrites is presented. The possible interpretations of this distribution are reviewed at the global scale of the solar system planetary objects and at the scale defined by the carbonaceous meteorites. New issues concerning the chemical origin of the deuterium enrichment in solar system water and organic molecules are put into light by this exercise. This distribution is a robust constraint on the origin of water on Earth.
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Aléon, J., Engrand, C., Robert, F., and Chaussidon, M.: 2001, 'Clues to the Origin of Interplanetary Dust Particles from the Isotopic Study of their Hydrogen-bearing Phases', Geochim. Cosmochim. Acta 65, 4399–4412.
André, P., and Montmerle, T.: 1994, 'From T Tauri Stars to Protostars: Circumstellar Material and Young Stellar Objects in the p-Ophiuchi Cloud', Astrophys. J. 420, 837–862.
Balsiger, H., Altwegg, K., and Geiss, J.: 1995, 'D/H and 18O/16O Ratio in the Hydronium Ion and in Neutral Water from in Situ Ion Measurements in Comet P/Halley', J. Geophys. Res. 100, 5827–5834.
Becker, R.H., and Epstein, S.: 1982, 'Carbon, Hydrogen, and Nitrogen Isotopes in Solvent-extractable Organic Matter from Carbonaceous Chondrites', Geochim. Cosmochim. Acta 46, 97–103.
Boato, G.: 1954, 'The Isotopic Composition of Hydrogen and Carbon in the Carbonaceous Chondrites', Geochim. Cosmochim. Acta 6, 209–220.
Bockelée-Morvan, D., Gautier, D., Lis, D.C., Young, K., Keene, J., Phillips, T., Owen, T., Crovisier, J., Goldsmith, P.F., Bergin, E.A., Despois, D., and Wootten, A.: 1998, 'Deuterated Water in Comet C/1996 B2 (Hyakutake) and its Implications for the Origin of Comets', Icarus 133, 147–162.
Brown, P.D., and Millar, T.J.: 1989, 'Models of the Gaz-grain Interaction-Deuterium Chemistry', Mon. Not. Roy. Astron. Soc. 237, 661–671.
Brown, R.D., and Rice, E.: 1981, 'Interstellar Deuterium Chemistry', Phil. Trans. Roy. Soc. London A303, 523–533.
Bunch, T.E., and Chang, S.: 1980, 'Carbonaceous Chondrite: II. Carbonaceous Chondrites Phyllosilicates and Light Element Geochemistry as Indicators of Parent Body Processes and Surface Conditions', Geochim. Cosmochim. Acta 44, 1543–1577.
Cassen, P.: 1994, 'Utilitarian Models of the Solar Nebula', Icarus 112, 405–429.
Chiang, E.I., Joung, M.K., Creech-Eakman, M.J., Qi, C., Kessler, J.E., Blake, G.A., and van Dishoeck, E.F.: 2001, 'Spectral Energy Distributions of Passive T Tauri and Herbig Ae Disks: Grain Mineralogy, Parameter Dependences and Comparison with Infrared Space Observatory LWS Observations', Astrophys. J. 547, 1077–1089.
Dauphas, N., Robert, F., and Marty, B.: 2000, 'The Late Asteroidal and Cometary Bombardment of Earth as Recorded in Water Deuterium to Protium Ratio', Icarus 148, 508–512.
Deloule, E., and Robert, F.: 1995, 'Interstellar Water in Meteorites?', Geochim. Cosmochim. Acta 59, 4695–4706.
Deloule, E., Doukhan, J.-C., and Robert, F.: 1998, 'Interstellar Hydroxyle in Meteorite Chondrules: Implications for the Origin of Water in the Inner Solar System', Geochim. Cosmochim. Acta 62, 3367–3378.
Drake, M.J., and Righter, K.: 2002, 'Determining the Composition of the Earth', Nature 416, 39–44.
Drouart, A., Dubrulle, B., Gautier, D., and Robert, F.: 1999, 'Structure and Transport in the Solar Nebula from Constraints on Deuterium Enrichment and Giant Planet Formation', Icarus 140, 129–155.
Dubrulle, B.: 1992, 'A Turbulent Closure Model for Thin Accretion Disks', Astron. Astrophys. 266, 592–604.
Eberhardt, P., Dolder, U., Schulte, W., Krankowsky, D., Lammerzahl, P., Hoffmann, J.H., Hodges, R.R., Berthelier, J.J., and Illiano, J.M.: 1987, 'The D/H Ratio in Water from Comet p/Halley', Astron. Astrophys. 187, 435–437.
Eiler, J.M., and Kitchen, N.: 2002a, 'Hydrogen-isotope Geochemistry of the CM Chondrites', Abstract presented at the 2002 Goldschmidt Conf. in Davos.
Eiler, J.M., and Kitchen, N.: 2002b, 'Hydrogen Isotope Evidence for the Origin and Evolution of the CM Carbonaceous Chondrites', Geochim. Comochim. Acta, in preparation.
Encrenaz, T., and Owen, T.: 2003, 'Element Abundances and Isotope Ratios in the Giant Planets and Titan', Space Sci. Rev., this volume.
Engrand, C., Deloule, E., Robert, F., Maurette M., and Kurat, G.: 1999, 'Extraterrestrial Water in Micrometeorites and Cosmic Spherules from Antarctica: An Ion Microprobe Study', Met. Planet. Sci. 34, 773–786.
Epstein, S., Krishnamurty, R.V., Cronin, J.R., Pizzarello, S., and Yuen, G.U.: 1987, 'Unusual Stable Isotope Ratios in Amino Acids and Carboxylic Acid Extracts from the Murchison Meteorite', Nature 326, 477–479.
Geiss, J., and Gloecker, G.: 1998, 'Abundances of Deuterium and Helium in the Protosolar Cloud', Space Sci. Rev. 84, 239–250.
Gensheimer, P.D., Mauersberger, R., and Wilson, T.L.: 1996, 'Water in Galactic Hot Cores', Astron. Astrophys. 314, 281–294.
Glassgold, A., Feigelson, E.D., and Montmerle, T.: 2000, 'Effects on Energetic Radiation in Young Stellar Objects', in V. Mannings, A.P. Boss, and S.S. Russel (eds.), Protostars and Planets IV, University of Arizona Press, Tucson, pp. 429–455.
Guélin, M., Langer, W.D., and Wilson, R.W.: 1982, 'The State of Ionization in Dense Molecular Clouds', Astron. Astrophys. 107, 107–127.
Halbout, J., Robert, F., and Javoy, M.: 1990, 'Hydrogen and Oxygen Isotope Compositions in Kerogens from the Orgueil Meteorite: Clues to Solar Origin', Geochim. Cosmochim. Acta 54, 1453–1462.
Hersant, F., Gautier, D., Huré, J.-M.: 2001, 'A Two-dimensional Model for the Primordial Nebula Constrained by D/H Measurements in the Solar System: Implications for the Formation of Giant Planets', Astrophys. J. 554, 391–407.
Jacq, T., Walmzey, C.M., Henkel, C., Baudry, R., Mauersberger, R., and Jewell, P.R.: 1990, 'Deuterated Water and Ammonia in Hot Cores', Astron. Astrophys 228, 447–458.
Kerridge, J.F.: 1985, 'Carbon, Hydrogen, and Nitrogen in Carbonaceous Meteorites: Abundances and Isotopic Compositions in Bulk Samples', Geochim. Cosmochim. Acta 49, 1707–1714.
Kerridge, J.F., Chang, S., and Shipp, R.: 1987, 'Isotope Characterisation of Kerogen-like Material in Murchison Carbonaceous Chondrite', Geochim. Cosmochim. Acta 51, 2527–2540.
Kolodny, Y., Kerridge, J.F., and Kaplan, I.R.: 1980, 'Deuterium in Carbonaceous Chondrites', Earth Planet. Sci. Lett. 46, 149–158.
Krishnamurthy, R.V., Epstein, S., Cronin, J.R., Pizzarello, S., and Yuen, G.U.: 1992, 'Isotopic and Molecular Analyses of Hydrocarbons and Monocarboxylic Acids of the Murchison Meteorite', Geochim. Cosmochim. Acta 56, 4045–4058.
Lécluse, C., and Robert, F.: 1994, 'Hydrogen Isotope Exchange Rates: Origin of Water in the Inner Solar System', Geochim. Cosmochim. Acta 58, 2297–2939.
Lécuyer, C., Gillet, P., and Robert, F.: 1998, 'The Hydrogen Isotope Composition of Sea Water and the Global Water Cycle', Chem. Geology 145, 249–261.
Lellouch, E., Bézard, B., Feuchtgruber, T., Encrenaz, T., and de Graauw, T.: 2001, 'The Deuterium Abundance in Jupiter and Saturn from ISO-SWS Observations', Astron. Astrophys. 370, 610–622.
Linsky, J.L., Brown, A., Gayley, K., Diplas, A., Savage, B.D., Landsman, T.R., Shore, S.N., and Heap, S.R.: 1993, 'High-Resolution Spectrograph Observations of the Local Interstellar Medium and the D/H Ratio along the Line of Sight toward Capella', Astrophys. J. 402, 694–709.
Mahaffy, P.R., Donahue, T.M., Atreya, S.K., Owen, T.C., and Niemann, H.B.: 1998, 'Galileo Probe Measurements of D/H and 3He/4 He in Jupiter's Atmosphère', Space Sci. Rev. 84, 251–263.
McCullough, P.R.: 1992, 'The Interstellar Deuterium to Hydrogen Ratio: A Reevaluation of Lyman Absorbtion Line Measurements', Astrophys. J. 390, 213–225.
McNaughton, N.J., Borthwicks, S., Fallick, A.K., and Pillinger, C.T.: 1981, 'D/H Ratio in Unequilibrated Ordinary Chondrites', Nature 294, 639–641.
McNaughton, N.J., Fallick, A.E., and Pillinger, C.T.: 1982, 'Deuterium Enrichments in Type 3 Ordinary Chondrites', J. Geophys. Res. 87, 294–302.
Meier, R., Owen, T.C., Matthews, H.E., Bockelée-Morvan, D.K., Biver, N., Crovisier, J., and Gautier, D.: 1998a, 'A Determination of the HDO/H2O Ratio in Comet C/1995 O1 (Hale-Bopp)', Science 279, 842–844.
Meier, R., Owen, T.C., Matthews, H.E., Bockelée-Morvan, D., Biver, N., Crovisier, J., and Gautier, D.: 1998b, 'A Determination of the HDO/H2O Ratio in Comet C/1995 O1 (Hale-Bopp)', Science 279, 842–844.
Messenger, S., Stadermann, F.J., Floss, C., Nittler, L.R., and Mukhopadyay, S.: 2003, 'Isotopic Signatures of Presolar Materials in Interplanetary Dust', Space Sci. Rev., this volume.
Millar, T.J., Bennett, A., and Herbst, E.: 1989, 'Deuterium Fractionation in Dense Interstellar Clouds', Astrophys. J. 340, 906–920.
Millar, T.J.: 2002, Proc. Meudon Symposium 2001: Deuterium in the Universe, personal communication and Planet. Space Sci., in press.
Morbidelli, A., Chambers, J., Lunine, J., Petit, J.M., Robert, F., and Valsecchi, G.B.: 2000, 'Source Regions and Timescales for the Delivery of Water on Earth', Met. Planet. Sci. 35, 1309–1320.
Mousis, O., Gautier, D., Bockelée-Morvan, D., Robert, F., Dubrulle, B., and Drouart, A.: 2000, 'Constraints on the Formation of Comets from D/H Ratios Measured in H2O and HCN', Icarus 148, 513–525.
Pearson, V.K., Sephton, M.A., Gilmour, I., and Franchi, I.A.: 2001, 'Hydrogen Isotopic Composition of the Tagish Lake Meteorite: Comparison with other Carbonaceous Chondrites', Lunar Planet. Sci. XXXII, abstract # 1861.
Pizzarello, S., Krishnamurthy, R.V., Epstein, S., and Cronin, J.R.: 1991, 'Isotopic Analysis of Amino Acids from the Murchison Meteorite', Geochim. Cosmochim. Acta 55, 905–910.
Robert, F.: 2001, 'The Origin of Water on Earth', Science 293, 1056–1058.
Robert, F.: 2002, 'Water and Organic Matter in the Solar System as a Record of an Early Irradiation of the Protosolar Nebula', Proc. Meudon Symposium 2001: Deuterium in the Universe, Planet. Space Sci., in press.
Robert, F., and Epstein, S.: 1982, 'The Concentration of Isotopic Compositions of Hydrogen, Carbon, and Nitrogen in Carbonaceous Chondrites', Geochim. Cosmochim. Acta 16, 81–95.
Robert, F., and Deloule, E.: 2002, 'Using the D/H Ratio to Estimate the Terrestrial Water Contamination in Chondrites', Lunar Planet. Sci. Conf. XXXIII, 1299–1300 (pdf file).
Robert, F., Merlivat, L., and Javoy, M.: 1979, 'Deuterium Concentration in the Early Solar System: A Hydrogen and Oxygen Isotopic Study', Nature 282, 785–789.
Robert, F.M., Javoy, J., Halbout, B., Dimon, B., and Merlivat, L.: 1987a, 'Hydrogen Isotopes Abundances in the Solar System, Part I: Unequilibrated Chondrites', Geochim. Cosmochim. Acta 51, 1787–1806.
Robert, F.M., Javoy, J., Halbout, B., Dimon, B., and Merlivat, L.: 1987b, 'Hydrogen Isotope Abundances in the Solar System, Part II: Meteorites with Terrestrial Like D/H Ratios', Geochim. Cosmochim. Acta 51, 1807–1822.
Robert, F., Gautier, D., and Dubrulle, B.: 2000, 'The Solar System D/H Ratio: Observations and Theories', in W. Benz, R. Kallenbach, and G.W. Lugmair (eds.), From Dust to Terrestrial Planets, Kluwer Acadmic Publishers, Dordrecht, Space Sci. Rev. 92, 201–224.
Rodgers, S.D., and Millar, T.J.: 1996, 'The Chemistry of Deuterium in Hot Molecular Cores', Month. Not. Roy. Astron. Soc. 280, 1046–1054.
Sandford, S.A., Bernstein, M.P., and Dworkin, J.P.: 2001, 'Assessment of the Interstellar Processes Leading to Deuterium Enrichment in Meteoritic Organics', Met. Planet. Sci. 36, 1117–1133.
Sears, D.W.G., Morse, A.D., Hutchison, R., Guimon, K.R., Jie, L., Alexander, C.M.O'D., Benoit, P.H., Wright, I., Pillinger, C., Xie, T., and Lipschutz, M.E.: 1995, 'Metamorphism and Aqueous Alteration in Low Petrographic Type Ordinary Chondrites', Meteoritics 30, 169–181.
Vokrouhlicky, D., and Farinella, P.: 2000, 'Efficient Delivery of Meteorites to the Earth from a Wide Range of Asteroid Parent Bodies', Nature 407, 606–608.
Willacy, K., and Millar, T.J.: 1998, 'Adsorption Processes and the Deuterium Fractionation in Molecular Clouds', Month. Not. Roy. Astron. Soc. 228, 562–568.
Yang, J., and Epstein, S.: 1983, 'Interstellar Organic Matter in Meteorites', Geochim. Cosmochim. Acta 47, 2199–2216.
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Robert, F. The D/H Ratio in Chondrites. Space Science Reviews 106, 87–101 (2003). https://doi.org/10.1023/A:1024629402715
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DOI: https://doi.org/10.1023/A:1024629402715