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High-temperature structural change of CrOx-LaOx-Al2O3 catalyst for lean-burn exhaust treatment

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Abstract

Solid-state reaction in the system of CrOx-Al2O3 and CrOx-LaOx-Al2O3 and their sintering at 500–1100°C were examined by X-ray diffraction, electron spin resonance (ESR) and surface area measurement for the development of heat-stable catalytic ceramic in lean-burn exhaust treatment. CrOx-LaOx-Al2O3 catalyst, even heated at 1000°C in air, showed the removal conversion of 100% for C3H6, 95% for CO and 7% for NO at 500°C for high velocity automotive lean-burn exhaust with A/F = 18 and S.V. = 105h−1. La-modification of catalyst was effective to high surface area stabilization and the improvement of complete oxidation activity of CO and hydrocarbons.

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References

  1. K. C. Taylor, in “Catalysis Science and Technology,” Vol. 8, edited by J. R. Anderson and M. Boudart (Springer-Verlag, Berlin-NY, 1984) p. 120.

    Google Scholar 

  2. N. Miyoshi, T. Tanaka and S. Matsumoto, Toyota Tech. Review 50 (2000) 28.

    Google Scholar 

  3. S. Matsumoto, Catal. Today 29 (1996) 43.

    Google Scholar 

  4. W. Held, A. Konig, T. Richter and L. Puppe, SAE Paper No. 900496 (Soc. Automotive Engn., 1990) p. 1.

  5. M. Iwamoto and H. Hamada, Catal. Today 10 (1991) 57.

    Google Scholar 

  6. H. Hamada, Y. Kintaichi, M. Sasaki and T. Ito, Appl. Catal. 75 (1991) L1.

    Google Scholar 

  7. Idem., ibid. 70 (1991) L15.

  8. Y. Kintaichi, H. Hamada, M. Tabata, M. Sasaki and T. Ito, Catal. Lett. 6 (1991) 239.

    Google Scholar 

  9. Y. Torikai, H. Yahiro, N. Mizuno and M. Iwamoto, ibid. 9 (1991) 91.

    Google Scholar 

  10. K. C. C. Kharas, H. J. Robota and D. J. Liu, Appl. Catal. B 2 (1993) 225.

    Google Scholar 

  11. G. P. Ansell, A. F. Diwell, S. E. Golunski, J. W. Hayes, R. R. Rajaram, T. J. Truex and A. P. Walker, ibid. 2 (1993) 81.

    Google Scholar 

  12. R. A. Grinsted, H.-W. Jen, C. N. Montreuil, M. J. Rokosz and M. Shelef, Zeolites 13 (1993) 602.

    Google Scholar 

  13. S. Matsumoto, K. Yokota, H. Doi, M. Kimura, K. Sekikawa and S. Kasahara, Catal. Today 22 (1994) 127.

    Google Scholar 

  14. M. Ozawa, H. Toda, O. Kato and S. Suzuki, Appl. Catal. B 8 (1996) 123.

    Google Scholar 

  15. M. Ozawa, S. Suzuki and H. Toda, J. Amer. Ceram. Soc. 80 (1997) 1957.

    Google Scholar 

  16. M. Ozawa, O. Kato and S. Suzuki, J. Mater. Sci. 33 (1998) 737.

    Google Scholar 

  17. M. Ozawa, M. Kimura and A. Isogai, J. Alloy Compd. 193 (1993) 73.

    Google Scholar 

  18. Idem., J. Less-Comon Met. 162 (1990) 297.

    Google Scholar 

  19. G. C. Bye and G. T. Simpkin, J. Amer. Ceram. Soc. 57 (1974) 367.

    Google Scholar 

  20. D. E. O'Reilly and D. S. Macivwe, J. Phys. Chem. 66 (1962) 276.

    Google Scholar 

  21. C. J. Carman and W. J. Kroenke, ibid. 72 (1968) 2562.

    Google Scholar 

  22. L. Forni and C. Oliva, J. Chem. Soc. Faraday Trans. I 84 (1988) 2477.

    Google Scholar 

  23. X. Zhang, A. B. Walters and M. A. Vannice, Appl. Catal. B 4 (1994) 237.

    Google Scholar 

  24. B. Dziewiecka and Z. Dziewiecki, Catalysis Today 17 (1993) 121.

    Google Scholar 

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Correspondence to Masakuni Ozawa.

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Ozawa, M., Kato, O. & Suzuki, R. High-temperature structural change of CrOx-LaOx-Al2O3 catalyst for lean-burn exhaust treatment. Journal of Materials Science 38, 2607–2611 (2003). https://doi.org/10.1023/A:1024474316653

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