Water, Air, and Soil Pollution

, Volume 146, Issue 1–4, pp 35–54

The Chemical Composition of Precipitation in Madrid

  • C. Hontoria
  • A. Saa
  • J. Almorox
  • L. Cuadra
  • A. Sánchez
  • J. M. Gascó


The present study examines the chemical characteristics of first-fraction precipitation samples collected over a period of one year in Madrid, and patterns of temporal and spatial variation observed in their composition. One hundred and sixty-four samples of wet precipitation collected on an event basis were analysed for anions, cations, pH and electrical conductivity. Precipitation in Madrid was neutral, with only 3% of samples showing pH < 5.6. Dominant ions were calcium andsulphates. Calcium was the principal neutralizing agent, explaining 64% of all nitrates and sulphates. The marine influence did not appear to be relevant, while the soil seemed to play an important role in the composition of precipitation. Precipitation chemistry displayed seasonal differences, with higher concentrations of sulphates and chloride in autumn and winter and of calcium and sodium in the summer. There was an inverse relationship between concentrations and sample volumes; while the correlation between concentrations and the time elapsedsince the last rain event was positive, though poor for normalized concentrations. Four variables (sample volume, days elapsed since the last rain event, maximum wind gust direction and season) explained to a large extent (more than 90% for some sampling stations) the variability of certain chemical variables.

correlation meteorological conditions precipitation volume Spain urban precipitation chemistry 


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  1. Aggarwal, S. G., Chandrawanshi, C. K., Patel, R.M., Agarwal, S., K amavisdar, A. and Mundhara, G. L.: 2001, ‘Acidification of surface water in Central India’, Water, Air, and Soil Pollut. 130(1-4), 855-862.Google Scholar
  2. Agrawal, M. and Singh, R. K.: 2001, ‘Effect of industrial emission on atmospheric wet deposition’, Water, Air, and Soil Pollut. 130(1-4), 481-486.Google Scholar
  3. Al-Monani, I. F., Ataman, O. Y., Anwari, M. A., Tuncel, S., Köse, C. and Tuncel, G.: 1995, ‘Chemical composition of precipitation near an industrial area at Izmir, Turkey’, Atmos. Environ. 29(10), 1131-1143.Google Scholar
  4. Ávila, A.: 1996, ‘Time trends in the precipitation chemistry at a mountain site in north-eastern Spain for the period 1983-1994’, Atmos. Environ. 30(9), 1363-1373.Google Scholar
  5. Ávila, A. and Alarcón, M.: 1999, ‘Relationship between precipitation chemistry and meteorological situations at a rural site in NE Spain’, Atmos. Environ. 33, 1663-1677.Google Scholar
  6. Brueggemann, E., and Rolle, W.: 1998, ‘Changes of some components of precipitation in East Germany after the unification’, Water, Air, and Soil Pollut. 107, 1-23.Google Scholar
  7. Cabon, J. Y.: 1999, ‘Chemical characteristics of precipitation at an Atlantic station’, Water, Air, and Soil Pollut. 111, 399-416.Google Scholar
  8. Camarero, L. and Catalan, J.: 1993, ‘Chemistry of bulk precipitation in the central and eastern Pyrenees, northeast Spain’, Atmos. Environ. 27A(1), 83-94.Google Scholar
  9. Cape, J. N., Fowder, D., Kinnaird, J. W., Paterson, I. S., Leith, I. D. and Nicholson, I. A.: 1984, ‘Chemical composition of rainfall and wet deposition over northern Britain’, Atmos. Environ. 18(9), 1921-1932.Google Scholar
  10. Carratalá, A. and Bellot, J.: 1998, ‘Neutralization of nitrate and sulphate in precipitation on the eastern mediterranean coast of Spain. Implications for acidification’, Water, Air, and Soil Pollut. 104, 237-257.Google Scholar
  11. Carratalá, A., Gómez, A. and Bellot, J.: 1998, ‘Mapping rain composition in the east of Spain by applying kriging’, Water, Air, and Soil Pollut. 104, 9-27.Google Scholar
  12. Casado, H., Encinas, D. and Lacaux, J. P.: 1996, ‘Relationship between the atmospheric particulate fraction and the ionic content of precipitation in an area under influence of a waste incinerator located in the Basque Country (Spain)’, Atmos. Environ. 30(10-11), 1537-1542.Google Scholar
  13. Cheng, S. and Lam, K. C.: 2000, ‘Synoptic typing and its application to the assessment of climatic impact on concentrations of sulfur dioxide and nitrogen oxides in Hong-Kong’, Atmos. Environ. 34, 585-594.Google Scholar
  14. Conlan, D. E., Lindley, S. J. and Longhurst, J. W. S.: 1995, ‘Spatial and temporal variability in precipitation chemistry in the urban area of Greater Manchester’, Water, Air, and Soil Pollut. 85, 2095-2100.Google Scholar
  15. Díaz-Caneja, N., Bonet, A., Gutiérrez, I., Martínez, A. and Villar, E.: 1989, ‘The chemical composition of rainfall in a city of northern Spain’, Water, Air, and Soil Pollut. 43, 277-291.Google Scholar
  16. Dikaiakos, J. G., Tsitouris, C. G., Siskos, P. A., Melissos, D. A. and Nastos, P.: 1990, ‘Precipitation composition in Athens, Greece’, Atmos. Environ. 24B(1), 171-176.Google Scholar
  17. Emberson, L. D., Ashmore, M. R., Murray, F., K uylenstierna, J. C. I., Percy, K. E., Izuta, T., Zheng, Y., Shimizu, H., Sheu, B. H., Liu, C. P., Agrawal, M., Wahid, A., Abdel-Latif, N. M., Van Tienhoven, M., De Bauer, L. I. and Domingos, M.: 2001, ‘Impacts of air pollutants on vegetation in developing countries’, Water, Air, and Soil Pollut. 130(1-4), 107-118.Google Scholar
  18. Encinas, D. and Casado, H.: 1999, ‘Rain-aerosol coupling in a rural area in the Basque Country (Spain): Scavenging ratios’, Aerosol Sci. Tech. 30(5), 411-419.Google Scholar
  19. Ezcurra, A., Casado, H., Lacaux, J. P. and García, C.: 1988, ‘Relationships between meteorological situations and acid rain in Spanish Basque Country’, Atmos. Environ. 22, 2779-2786.Google Scholar
  20. Fujita, S., Takahashi, A., Weng, J., Huang, L., Kim, H., Li, C., Huang, F. T. C. and Jeng, F.: 2000, ‘Precipitation chemistry in East Asia’, Atmos. Environ. 34, 525-537.Google Scholar
  21. Galloway, J. N. and Gaudry, A.: 1984, ‘The composition of precipitation on Amsterdam island, Indian Ocean’, Atmos. Environ. 18, 2649-2656.Google Scholar
  22. Granat, L., Suksomsankh, K., Simachaya, S., Tabucanon, M. and Rodhe, H.: 1996, ‘Regional background acidity and chemical composition of precipitation in Thailand’, Atmos. Environ. 30, 1589-1596.Google Scholar
  23. Hayashi, K., Igarashi, Y., Tsutsumi, Y. and Dokiya, Y.: 2001, ‘Aerosol and precipitation chemistry during the summer at the summit of Mt. Fuji, Japan (3776 m a.s.l.)’, Water, Air, and Soil Pollut. 130(1-4), 1667-1672.Google Scholar
  24. Jaradat, Q. M., Momani, K. A., Jiries, A. G., El-Alali, A., Batarseh, M. I., Sabri, T. G. and Al-Momani I. F.: 1999, ‘Chemical composition of urban wet deposition in Amman, Jordan’, Water, Air, and Soil Pollut. 112, 55-65.Google Scholar
  25. Jordan, T. E., Correl, D. L., Weller, D. E. and Goff, N. M.: 1995, ‘Temporal variation in precipitation chemistry on the shore of Chesapeake Bay’, Water, Air, and Soil Pollut. 83, 263-284.Google Scholar
  26. Kanazu, T., Matsumura, T., Nishiuchi, T. and Yamamoto, T.: 2001, ‘Effect of simulated acid rain on deterioration of concrete’, Water, Air, and Soil Pollut. 130(1-4), 1481-1486.Google Scholar
  27. Kitamura, S. I. and Ikuta, K.: 2001, ‘Effects of acidification on salmonid spawning behavior’, Water, Air, and Soil Pollut. 130(1-4), 875-880.Google Scholar
  28. Kulshrestha, U. C., Kulshrestha, M. J., Sekar, R., Vairamani, M., Sarkar, A. K. and Parashar, D. C.: 2001, ‘Investigation of alkaline nature of rain water in India’, Water, Air, and Soil Pollut. 130(1-4), 1685-1690.Google Scholar
  29. Künzli, N., Kaiser, R., Medina, S., Studnicka, M., Chanel, O., Filliger, P., Herry, M., Horak, F., Puybonnieux-Texier Jr., V., Quénel, P., Schneider, J., Seethaler, R., Vergnaud, J.-C. and Sommer, H.: 2000, ‘Public-health impact of outdoor and traffic-related air pollution: An European assessment’, Lancet 356, 795-801.Google Scholar
  30. Larssen, T. and Carmichael, G. R.: 2000, ‘Acid rain and acidification in China: The importance of base cation deposition’, Environ. Pollut. 110, 89-102.Google Scholar
  31. Lee, B. K., Hong, S. H. and Lee, D. S.: 2000, ‘Chemical composition of precipitation and wet deposition of major ions on the Korean peninsula’, Atmos. Environ. 34, 563-575.Google Scholar
  32. Lee, D. S. and Longhurst, J. W. S.: 1992, ‘A statistical intercomparison between ‘urban’ and ‘rural’ precipitation chemistry data from greater Manchester and two nearby secondary national network sites in the United Kingdom’, Atmos. Environ. 26, 2869-2883.Google Scholar
  33. Lumbreras, J., Urquiza, G. and Rodríguez, M. E.: 2002, ‘Emission Inventory and Emission Factor Projections for Modeling Air Pollution in the CAM (Spain)’, Proceedings of the 11th International Emission Inventory Conference: ‘Emission Inventories - Partnering for the Future’, Atlanta (EEUU).Google Scholar
  34. Mamane, Y. and Gottlieb, J.: 1995, ‘Ten years of precipitation chemistry in Haifa, Israel’, Water, Air, and Soil Pollut. 82, 549-558.Google Scholar
  35. MMA: 2000, ‘Inventario de emisiones de contaminantes a la atmósfera CORINE-AIRE 1994, 1995 y 1996’, Ministerio de Medio Ambiente, Madrid.Google Scholar
  36. Park, S. and Lee, Y.: 2001, ‘Mapping of base cation deposition in South Korea’, Water, Air, and Soil Pollut. 128, 297-312.Google Scholar
  37. Raddum, G. G., Skjelkvåle, B. L.: 2001, ‘Critical limit of acidifying compounds to invertebrates in different regions of Europe’, Water, Air, and Soil Pollut. 130(1-4), 825–830.Google Scholar
  38. Rajsic, S., Otten, P. and Van Grieken, R.: 1991, ‘Chemical composition of rain water in Antwerp, Belgium’, Environ. Tech. 12, 257-261.Google Scholar
  39. Rodà, F., Bellot, J., Ávila, A., Escarré, A., Piñol, J. and Terradas, J.: 1993, ‘Saharan dust and the atmospheric inputs of elements and alkalinity to Mediterranean ecosystems’, Water, Air, and Soil Pollut. 66, 277-288.Google Scholar
  40. Samara, C., Tsitouris, C. G. and Balafoutis, C.: 1992, ‘Chemical composition of rain in Thessaloniki, Greece, in relation to meteorological conditions’, Atmos. Environ. 26B(3), 359-367.Google Scholar
  41. Samara, C. and Tsitouridou, R.: 2000, ‘Fine and coarse ionic aerosol components in relation to wet and dry deposition’, Water, Air, and Soil Pollut. 120, 77-88.Google Scholar
  42. Sanusi, A., Wortham, H., Millet, M. and Mirabel, P.: 1996, ‘Chemical composition of precipitation in Eastern France’, Atmos. Environ. 10, 59-71.Google Scholar
  43. Satsangi, G. S., Lakhani, A., Khare, P., Singh, S. P., Kumari, K. M. and Srivastava, S. S.: 1998, ‘Composition of rain water at a semi-arid rural site in India’, Atmos. Environ. 32(21), 3783-3793.Google Scholar
  44. Seto, S., Oohara, M. and Ikeda, Y.: 2000, ‘Analysis of precipitation hemistry at a rural site in Hiroshima Prefecture, Japan’, Atmos. Environ. 34, 621-628.Google Scholar
  45. Singh, S. P., Khare, P., Satsangi, G. S., Lakhani, A., Maharaj Kumari, K. and Srivastava, S. S.: 2001, ‘Precipitation composition at a regional representative site of a semi-arid region of India’, Water, Air, and Soil Pollut. 127, 93-108.Google Scholar
  46. Stumm, W. and Morgan, J. J.: 1981, Aquatic Chemistry, John Wiley & Sons, New York, 780 p.Google Scholar
  47. Tuncel, S. G. and Ungör, S.: 1996, ‘Rain water chemistry in Ankara, Turkey’, Atmos. Environ. 30(5), 2721-2727.Google Scholar
  48. Vong, R. J., Larson, T. V., Covert, D. S. and Waggoner, A. P.: 1985, ‘Measurements and modelling of western Washington precipitation chemistry’, Water, Air, and Soil Pollut. 26, 71-84.Google Scholar
  49. Yagasaki, Y., Chishima, T., Okazaki, M., Jeon, D. S., Yoo, J. H., Kim, Y. K.: 2001, ‘Acidification of red pine forest soil due to acidic deposition in Chunchon, Korea’, Water, Air, and Soil Pollut. 130(1-4), 1085-1090.Google Scholar
  50. Zhang, F., Zhang, J., Zhang H., O gura, N. and Ushikubo, A.: 1996, ‘Chemical composition of precipitation in a forest area of Chongqing, Southwest China’, Water, Air, and Soil Pollut. 90, 407-415.Google Scholar

Copyright information

© Kluwer Academic Publishers 2003

Authors and Affiliations

  • C. Hontoria
    • 1
  • A. Saa
    • 1
  • J. Almorox
    • 1
  • L. Cuadra
    • 2
  • A. Sánchez
    • 2
  • J. M. Gascó
    • 1
  1. 1.Departamento de Edafología, Escuela Técnica Superior de Ingenieros AgrónomosUniversidad Politécnica de MadridMadridSpain (author for correspondence
  2. 2.Centro de Ciencias Medioambientales, CSIC, C/SerranoMadridSpain

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