Abstract
Extraction of lanthanides(III) [La(III)-Lu(III)] and yttrium(III) with toluene solution of trialkylbenzylammonium naphthenate mixture was studied. The equations of extraction isotherms taking into account formation of the extractable complexes (R4N)2[Ln(NO3)3A2] (A is naphthenate anion) were obtained. The extraction constants of lanthanides [La(III)-Lu(III] and yttrium(III) were calculated.
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Khol'kin, A.I. and Kuz'min, V.I., in Khimiya ekstraktsii (Extraction Chemistry), Novosibirsk, Nauka, 1984, pp. 533 67.
Gran, G., Determination of the Equivalence Point in Potentiometric Titration, Analyst, 1962, vol. 77, no. 920, pp. 6613 671.
Fedyanin, L.B., Stepanov, S.I., Sergievskii, V.V., and Frolov, Yu.G., —Khim. Tekhnol. Org. Vysokomol. Soedin., Tr. Mosk. Khim-Tekhnol. Inst. im. D.I. Mendeleeva, 1987, no. 80, pp. 20 325.
OST (Branch Standard) 48-209-81, revision no. 2, 1991: Rare-Earth Metal Oxides. Rules of Acceptance and Methods of Analysis.
Pyartman, A.K., Kovalev, S.V., Keskinov, V.A., and Kopyrin, A.A., Radiokhimiya, 1997, vol. 39, no. 2, pp. 145-148.
Rard, J.A., Miller, D.G., and Spedding, F.H., J. Chem. Eng. Data, 1977, vol. 24, no. 4, pp. 348-354.
Rard, J.A. and Spedding, F.H., J. Chem. Eng. Data, 1982, vol. 27, no. 4, pp. 451-461.
Rard, J.A. and Spedding, F.H., J. Chem. Eng. Data, 1981, vol. 26, no. 4, pp. 391-395.
Pitzer, K.S., Peterson, T.R., and Silvester, L.-F., J. Solution Chem., 1978, vol. 7, no. 1, pp. 45-46.
Chemical Thermodynamics in Industry: Models and Computation, Barry, T.I., Ed., Oxford: Blackwell Scientific, 1985.
Pyartman, A.K., Kovalev, S.V., and Keskinov, V.A., Radiokhimiya, 1997, vol. 39, no. 4, pp. 349-352.
Dennis, J.E. and Schnabel, R.B., Numerical Methods for Unconstrained Optimization and Nonlinear Equations, New Jersey: Prentice-Hall, 1983.
Bellamy, L.J., The Infra-Red Spectra of Complex Molecules, New York: Wiley, 1957.
Bellamy, L.J., Advances in Infrared Group Frequencies, London: Methuen, 1968.
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Pyartman, A.K., Kopyrin, A.A. & Zhikharev, D.A. Extraction of Lanthanide(III) and Yttrium(III) Nitrates with a Toluene Solution of Trialkylbenzylammonium Naphthenate. Russian Journal of Applied Chemistry 76, 55–59 (2003). https://doi.org/10.1023/A:1023335615099
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DOI: https://doi.org/10.1023/A:1023335615099