Skip to main content
Log in

Electrolytic decomposition of amaranth dyestuff using diamond electrodes

  • Published:
Journal of Applied Electrochemistry Aims and scope Submit manuscript

Abstract

The electrolytic decomposition of an amaranth dyestuff solution using several combinations of electrodes with diamond and platinum is reported. It is observed that a portion of the amaranth is decomposed on the cathode surface while the other portion is decomposed to lower molecular weight components on the anode surface. The decolourizing rate is higher at diamond electrodes used as the anode and the cathode than with other combinations. This electrode combination also shows a rapid decrease in total organic carbon concentration. Acetic acid and oxalic acid are detected as the intermediate substances, and CO2 gas is generated as a final product corresponding to the decrease in the oxalic acid concentration.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. G. Foti, D. Gandini, Ch. Comninellis, A. Perret and W. Haenni, Electrochem. Solid State Lett. 2 (1999) 228.

    Google Scholar 

  2. Gallegos and D. Pletcher, Electrochim. Acta 44 (1999) 2483.

    Google Scholar 

  3. D. Johnson, J. Feng and J. Houk, Electrochim. Acta 46 (2000) 323.

    Google Scholar 

  4. S. Stucki, R. Kotz, B. Carccer and W. Suter, J. Appl. Electrochem. 21 (1991) 909.

    Google Scholar 

  5. K. Kim, M. Kuppuswamy and R.F. Savinell, J. Appl. Electrochem. 30 (2000) 543.

    Google Scholar 

  6. G. Saracco, L. Solarino, R. Aigotti, V. Specchia and M. Maja, Electrochim. Acta 46 (2000) 373.

    Google Scholar 

  7. R. Amadelli, A. Battisti, D. Girenko, S. Kovalyov and A. Velichenko, Electrochim. Acta 46 (2000) 341.

    Google Scholar 

  8. Y.V. Pleskov, A.Y. Sakharova, M.D. Krotova, L.L. Bouilov and B.V. Spitsyn, J. Electroanal. Chem. 228 (1987) 19.

    Google Scholar 

  9. R. Tenne, K. Patel, K. Hashimoto and A. Fujishima, J. Electroanal. Chem. 347 (1993) 409.

    Google Scholar 

  10. G.M. Swain and R. Ramesham, Anal. Chem. 65 (1993) 345.

    Google Scholar 

  11. G.M. Swain, J. Electrochem. Soc. 141 (1994) 3382.

    Google Scholar 

  12. R. DeClements, B.L. Hirsche, M.C. Granger, J. Xu and G.M. Swain, J. Electrochem. Soc. 14 (1996) L150.

    Google Scholar 

  13. N. Katsuki, E. Takahashi, M. Toyoda, T. Kurosu, M. Iida, S. Wakita, Y. Nishiki and T. Shimamune, J. Electrochem. Soc. 145 (1998) 2358.

    Google Scholar 

  14. N. Katsuki, S. Wakita, Y. Nishiki, T. Shimamune, Y. Akiba and M. Iida, Jpn. J. Appl. Phys. 36 (1997) L260.

    Google Scholar 

  15. H.B. Martin, A. Argoitia, U. Landau, A.B. Anderson and J. Angus, J. Electrochem. Soc. 143 (1996) L133.

    Google Scholar 

  16. M. Granger and G. Swain, J. Electrochem. Soc. 146 (1999) 4551.

    Google Scholar 

  17. F. Bouamrane, A. Tadjeddine, R. Tenne, J.E. Butler, R. Kalish and Levy-Clement, J. Phys. Chem. B 102 (1998) 134.

    Google Scholar 

  18. Q. Chen, D. Gruen, A. Kraus and T. Corrigan, J. Electrochem. Soc. 148 (2001) E44.

    Google Scholar 

  19. B. Sarada, T. Rao, D. Tryk and A. Fijishima, J. Electrochem. Soc. 146 (1999) 1469.

    Google Scholar 

  20. T. Kuo, R. McCreery and G. Swain, Electrochem. Solid-State Lett. 2 (1999) 288.

    Google Scholar 

  21. N. Vinokur, B. Miller, Y. Avyigal and R. Kalish, J. Electrochem. Soc. 143 (1996) L238.

    Google Scholar 

  22. T. Yano, D. Tryk, K. Hashimoto and A. Fijishima, J. Electrochem. Soc. 145 (1998) 1870.

    Google Scholar 

  23. T. Yano, E. Popa, D. Tryk, K. Hashimoto and A. Fijishima, J. Electrochem. Soc. 146 (1999) 1081.

    Google Scholar 

  24. M. Panizza, I. Duo, P. M ichaud, G. Cerisola and Ch. Comninellis, Electrochem. Solid-State Lett. 3 (2000) 550.

    Google Scholar 

  25. F. Okino, H. S hibata, S. Kawasaki, H. Touhara, K. M omota, M. Gamo, I. Sakaguchi and T. Ando, Electrochem. Solid-State Lett. 2(1999) 382.

    Google Scholar 

  26. P. Michaud, E. Mahe, A. Perret, W. Haenni and Ch. Comninellis, Electrochem. Solid-State Lett. 3 (2000) 77.

    Google Scholar 

  27. S. Ferro, A. Battisti, I. Duo, Ch. Comninellis, W. Haenni and A. Perret, J. Electrochem. Soc. 147 (2000) 2614.

    Google Scholar 

  28. M. Fryda, D. Herrmann, L. Schafer, C. Klages, A. Perret, W. Haenni, Ch. Comninellis and D. Gandini, New Diamond and Frontier Carbon Tech. 9 (1999) 229.

    Google Scholar 

  29. D. Gandini, E. Mahe, P. Michaud, W. Haenni, A. Perret and Ch. Comninellis, J. App. Electrochem. 30 (2000) 1345.

    Google Scholar 

  30. E. Takahashi, T. Kurosu, K. Suga, Y. Nishiki, S. Wakita, M. Tanaka and S. Nakamatsu, Electrochem. (Denki Kagaku), in preparation.

  31. Y. Nakajima, M. Sekimoto, K. Hirao, T, Shimamune and Y. Matsuda, Electrochem. (Denki Kagaku) 62 (1994) 1086.

    Google Scholar 

  32. T.M. Florence, Electroanal. Chem. Int. Elec. 52 (1974) 115.

    Google Scholar 

  33. K. Suga, Y. Nishiki, M. Tanaka and S. Nakamatsu, Electrochem. (Denki Kagaku) 66 (1998) 856.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Y. Nishiki.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Hattori, S., Doi, M., Takahashi, E. et al. Electrolytic decomposition of amaranth dyestuff using diamond electrodes. Journal of Applied Electrochemistry 33, 85–91 (2003). https://doi.org/10.1023/A:1022945714152

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1022945714152

Navigation