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Effect of High Pressure on the Kinetics and Mechanism of Thermolysis of Organic Peroxides in Solution

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Abstract

This review analyzes published data and experimental results obtained by the authors concerning the effect of high pressure on the chemical kinetics of thermal decomposition of the main types of organic and organosilicon peroxides in solution. The volume effect of activation was found to depend on the mechanism of peroxide decomposition and on the properties of solvents.

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REFERENCES

  1. Antonovskii, V.L., Organicheskie perekisnye initsiatory (Organic Peroxide Initiators), Moscow: Khimiya, 1972.

    Google Scholar 

  2. Antonovskii, V.L., Khimicheskie istochniki svobodnykh radikalov (Chemical Sources of Free Radicals), Moscow: Znanie, 1980.

    Google Scholar 

  3. Antonovskii, V.L., Progress v khimii organicheskikh peroksidov (Advances in the Chemistry of Organic Peroxides), Moscow: TsNIITEneftekhim, 1992.

    Google Scholar 

  4. Antonovskii, V.L., Kinet. Katal., 1999, vol. 40, no.1, p. 163.

    Google Scholar 

  5. Golosov, A.P. and Dintses, A.I., Tekhnologiya proizvodstva polietilena i polipropilena (Technology of Polyethylene and Polypropylene), Moscow: Khimiya, 1978.

    Google Scholar 

  6. Seidl, H. and Luft, G., J. Macromol. Sci. Chem., 1981, vol. 15, p. 1.

    Google Scholar 

  7. Luft, G., Bitsch, H., and Seidl, H., J. Macromol. Sci. Chem., 1977, vol. 11, p. 1089.

    Google Scholar 

  8. Luft, G., Mehrling, P., and Seidl, H., Angew Macromol. Chem. Phys., 1978, vol. 73, no.1118, p. 95.

    Google Scholar 

  9. Luft, G. and Seidl, H., Angew. Macromol. Chem. Phys., 1985, vol. 129, no.20, p. 61.

    Google Scholar 

  10. Luft, G., Lim, P.-C., Pavlakis, S., and Seidl, H., J. Macromol. Sci., 1985, vol. 22, p. 1183.

    Google Scholar 

  11. Luft, G., Hennig, W., and Dorn, M., Angew. Macromol. Chem. Phys., 1986, vol. 141, no.2306, p. 207.

    Google Scholar 

  12. Neuman, R.C., Acc. Chem. Res., 1972, vol. 5, p. 381.

    Google Scholar 

  13. Zhulin, V.M., Rev. Phys. Chem., 1980, vol. 50, p. 217.

    Google Scholar 

  14. El'yanov, B.C. and Vasylvitskaya, E.M., Rev. Phys. Chem., 1980, vol. 50, p. 169.

    Google Scholar 

  15. Zhulin, V.M. and Stashina, G.A., Khimiya organicheskikh peroksidov (The Chemistry of Organic Peroxides), Emanuel', N.M., Ed., Volgograd: PI, 1982, p. 63.

    Google Scholar 

  16. Zhulin, V.M., Fizicheskaya khimiya. Sovremennye problemy (Physical Chemistry: Current Problems), Kolotyrkina, Ya.M., Ed., Moscow: Khimiya, 1984, p. 144.

    Google Scholar 

  17. El'yanov, B.S., Vasil'vitskaya, E.M., Zhulin, V.M., et al., Izv. Akad. Nauk SSSR, Ser. Khim., 1985, p. 1973.

  18. Zhulin, V.M., Lipovich, T.V., and Antonovskii, V.L., Izv. Akad. Nauk SSSR, Ser. Khim., 1988, p. 1516.

  19. Neuman, R.C. and Holmes, G.D., J. Am. Chem. Soc., 1971, vol. 93, p. 4242.

    Google Scholar 

  20. Neuman, R.C., Lockyer, G.D., and Amrich, M.I., Tetrahedron Lett., 1972, p. 1221.

  21. Neuman, R.C. and Lockyer, G.D., J. Am. Chem. Soc., 1983, vol. 105, p. 3982.

    Google Scholar 

  22. Le Noble, W.J., J. Chem. Educ., 1967, vol. 36, p. 729.

    Google Scholar 

  23. Bortnikov, M.Ya., Zlotskii, S.S., Zorin, V.V., et al., Izv. Akad. Nauk SSSR, Ser. Khim., 1977, p. 690.

  24. Pastushenko, E.V., Bortnikov, M.Y., Zlotskii, S.S., et al., React. Kinet. Catal. Lett., 1981, vol. 16, no.1, p. 195.

    Google Scholar 

  25. Buback, M. and Lendle, H., Z. Naturforsch., 1979, vol. 34, p. 1482.

    Google Scholar 

  26. Walling, C. and Metzger, G., J. Am. Chem. Soc., 1959, vol. 81, p. 5365.

    Google Scholar 

  27. Lipovich, T.V., Zhulin, V.M., and Antonovskii, V.L., Tez. dokl. VIII Vsesoyuznoi konferentsii po khimii organicheskikh peroksidov (Proc. VIII All-Union Conf. on the Chemistry of Organic Peroxides), Leningrad, 1985, p. 12.

  28. Schmidt, R., Steinmetzer, H.C., Brauer, H.D., et al., J. Am. Chem. Soc., 1976, vol. 98, p. 8181.

    Google Scholar 

  29. Lamb, R.C., Pacifici, I.G., and Ayers, P.W., J. Am. Chem. Soc., 1965, vol. 87, p. 3928.

    Google Scholar 

  30. Zhulin, V.M., Starostin, E.K., Moryasheva, S.I., and Nikishin, G.I., Izv. Akad. Nauk SSSR, Ser. Khim., 1979, p. 1237.

  31. Schulman, E.M., Merbach, A.E., and Le Noble, W.J., J. Org. Chem., 1982, vol. 47, p. 421.

    Google Scholar 

  32. Nickolson, A.E. and Norrish, G.D., Disc. Faraday Soc., 1956, vol. 22, p. 97.

    Google Scholar 

  33. Walling, C. and Pellon, J., J. Am. Chem. Soc., 1957, vol. 79, p. 4782.

    Google Scholar 

  34. Buback, M. and Hinton, C., Z. Phys. Chem., 1996, vol. 193, p. 61.

    Google Scholar 

  35. Buback, M. and Hinton, C., Z. Phys. Chem., 1997, vol. 199, p. 229.

    Google Scholar 

  36. Neuman, R.C. and Pankratz, R.P., J. Am. Chem. Soc., 1973, vol. 95, p. 8372.

    Google Scholar 

  37. Buback, M. and Lendle, H., Z. Naturforsch., 1981, vol. 36, p. 1371.

    Google Scholar 

  38. Mehrling, P., Luft, G., Giese, B., et al., Chem. Ber., 1985, vol. 118, p. 240.

    Google Scholar 

  39. Neuman, R.C. and Behar, J.V., J. Am. Chem. Soc., 1969, vol. 91, p. 6024.

    Google Scholar 

  40. Neuman, R.C. and Behar, J.V., J. Am. Chem. Soc., 1967, vol. 89, p. 4549.

    Google Scholar 

  41. Neuman, R.C. and Behar, J.V., J. Org. Chem., 1971, vol. 36, p. 654.

    Google Scholar 

  42. Neuman, R.C. and Wolfe, R., J. Org. Chem., 1975, vol. 40, p. 3147.

    Google Scholar 

  43. Zhulin, V.M., Rudakov, O.B., Stashina, G.A., et al., Izv. Akad. Nauk SSSR, Ser. Khim., 1985, p. 1979.

  44. Marriott, P.R. and Griller, D., J. Am. Chem. Soc., 1981, vol. 103, p. 1521.

    Google Scholar 

  45. Yablokov, V.A., Ganyushkin, A.V., Bortnikov, M.Ya., et al., Izv. Akad. Nauk SSSR, Ser. Khim., 1978, p. 484.

  46. Yablokov, V.A., Ganyushkin, A.V., Bortnikov, M.Ya., et al., Izv. Akad. Nauk SSSR, Ser. Khim., 1980, p. 950.

  47. Bull, T.E. and Jonas, J., J. Chem. Phys., 1946, vol. 52, p. 4553.

    Google Scholar 

  48. Parhkurst, H., Lee, Y., and Jonas, J., J. Chem. Phys., 1971, vol. 55, p. 1368.

    Google Scholar 

  49. Jonas, J., Ann. Rev. Phys. Chem., 1975, vol. 26, p. 167.

    Google Scholar 

  50. Ganyushkin, A.V., Yablokov, V.A., Stashina, G.A., et al., VII Vsesoyuznoi konferentsii po khimii organicheskikh peroksidov (Proc. VII All-Union Conf. on the Chemistry of Organic Peroxides), Volgograd, 1980, p. 235.

  51. Zhulin, V.M., Stashina, G.A., Ganyushkin, A.V., et al., Izv. Akad. Nauk SSSR, Ser. Khim., 1983, p. 1659.

  52. Zhulin, V.M., Rudakov, O.B., Ganyushkin, A.V., et al., Izv. Akad. Nauk SSSR, Ser. Khim., 1986, p. 2206.

  53. Walling, C., Moulden, H.N., Waters, J.H., and Neuman, R.C., J. Am. Chem. Soc., 1965, vol. 87, p. 518.

    Google Scholar 

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Authors and Affiliations

  1. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, 119991, Russia

    V. L. Antonovskii

  2. Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, 119992, Russia

    V. M. Zhulin

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  1. V. L. Antonovskii
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  2. V. M. Zhulin
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Antonovskii, V.L., Zhulin, V.M. Effect of High Pressure on the Kinetics and Mechanism of Thermolysis of Organic Peroxides in Solution. Kinetics and Catalysis 44, 74–81 (2003). https://doi.org/10.1023/A:1022520717880

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