Abstract
The spectral sensitivity of Sn(II) complexes in acid and alkaline solutions of SnCl2 in photostimulated oxidation with oxygen was studied. The reaction mechanism was revealed. A spectrophotometric method for prompt monitoring of the composition of SnCl2 solutions was proposed.
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REFERENCES
Shalkauskas, M. and Vashkyalis, A., Khimicheskaya metallizatsiya plastmass (Electroless Metal Plating of Plastics), Leningrad: Khimiya, 1985, 3rd ed.
Sviridov, V.V., Vorob'eva, T.N., Gaevskaya, T.V., and Stepanova, L.I., Khimicheskoe osaszhdenie metallov iz vodnykh rastvorov (Electroless Deposition of Metals from Aqueous Solutions), Sviridov, V.V., Ed., Minsk: Universitetskoe, 1987.
Schlesinger, M. and Feldstein, N., J. Electrochem. Soc., 1973, vol. 120, pp. 236-241.
Dressik, W.J., Dulcey, C.S., Georger, J.H., et al., J. Electrochem. Soc., 1994, vol. 141, no. 1, pp. 210-220.
Putten, A.M.T. van der and Bakker, J.W.G. de, J. Electrochem. Soc., 1993, vol. 40, no. 8, pp. 2221-2228.
Reva, O.V. and Vorob'eva, T.N., Vestsi Akad. Navuk Bel., Ser. Khim. Navuk, 1995, no. 3, pp. 100-115.
Sard, R., J. Electrochem. Soc., 1970, vol. 117, pp. 864-870.
Cohen, R.L., D'Amico, I.F., and West, K.W., J. Electrochem. Soc., 1971, vol. 118, pp. 2042-2046.
Sharp, D.J., Plating, 1971, vol. 58, no. 8, pp. 786-790.
Reva, O.V., Vorob'eva, T.N., and Sviridov, V.V., Zh. Nauchn. Prikl. Fotogr. Kinematogr., 1999, vol. 44, no. 4, pp. 20-26.
Reva, O.V. and Vorob'eva, T.N., Zh. Prikl. Khim., 1998, vol. 71, no. 3, pp. 498-502.
Atkins, P.W., Physical Chemistry, Oxford: Oxford Univ. Press, 1994, 3rd ed.
Kutner, E. and Matseevskii, B., Kinet. Katal., 1969, vol. 10, no. 5, pp. 997-1003.
Zakharov, I., Karasevich, E., Shilov, A., and Shteinman, A., Kinet. Katal., 1975, vol. 14, no. 5, pp. 1151-1157.
Berentsveig, V., Pleskach, N., and Rudenko, A., Zh. Fiz. Khim., 1980, vol. 54, no. 12, pp. 222-236.
Razinkin, M., Berentsveig, V., and Rudenko, A., Vestn. Mosk. Gos. Univ., Ser. Khim., 1990, issue 31, no. 1, pp. 75387.
Petrite, L.I., Solutions of Palladium and Tin Compounds and Their Use in Electroless Metal Plating, Cand. Sci. Dissertation, Vilnius, 1981.
Paul, R.C., Sooch, K.S., Vaidya, O.S., and Narula, S.P., Anal. Chim. Acta, 1969, vol. 46, no. 1, pp. 131-137.
Calvert, J.G. and Pitts, J.N., Photochemistry, New York: Wiley, 1966.
Spravochnik khimika (Chemist's Handbook), Nikol'skii, B.P., Ed., Moscow: Khimiya, 1966, vol. 5.
Klyuchnikov, N.G., Rukovodstvo po neorganicheskomu sintezu (Manual on Inorganic Synthesis), Moscow: Khimiya, 1965.
Baudler, M., Brauer, J., Feher, F., et al., Handbuch der pr1aparativen anorganischen Chemie, Stuttgart: Enke, 1975. Translated under the title Rukovodstvo po neorganicheskomu sintezu, Moscow: Mir, 1985, vol. 3, pp. 669-1056.
Khimicheskaya entsiklopediya (Chemical Encyclopedia), Knunyants, I.L., Ed., Moscow: Bol'shaya Ross. Entsiklopediya, 1988, vol. 3.
Bohren, C.E. and Huffman, D.R., Absorption and Scattering of Light by Small Particles, New York: Wiley, 1983.
Reva, O.V., Chemical, Electrochemical, and Photochemical Transformations of Tin Compounds in Heterogeneous Systems, Cand. Sci. Dissertation, Minsk, 1999.
Vorob'eva, T.N., Barkovskaya, L.V., Stepanova, L.I., and Rukhlya, V.A., Vestsi Akad. Navuk Bel. SSR, Ser. Khim. Navuk, 1991, no. 5, pp. 106-111.
Vorob'eva, T.N., Reva, O.V., Rukhlya, V.A., et al., Vestsi Akad. Navuk Bel., Ser. Khim. Navuk, 1994, no. 2, pp. 94-100.
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Reva, O.V., Vorob'eva, T.N. Photostimulated Oxidation of Sn(II) in Aqueous Solutions: Spectral Sensitivity and Quantum Yield. Russian Journal of Applied Chemistry 75, 1399–1405 (2002). https://doi.org/10.1023/A:1022208424530
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DOI: https://doi.org/10.1023/A:1022208424530