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MCM-41 Anchored Cinchona Alkaloid for Catalytic Asymmetric Dihydroxylation of Olefins: A Clean Protocol for Chiral Diols Using Molecular Oxygen

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Abstract

MCM-41 anchored 1,4-bis(9-O-quininyl)phthalazine (MCM-(QN)2PHAL)-OsO4, is prepared for the first time and used in the heterogeneous asymmetric dihydroxylation of olefins to afford diols with good to excellent enantiomeric excesses in the presence of N-methylmorpholine N-oxide, K3Fe(CN)6 or molecular oxygen as cooxidants.

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Choudary, B.M., Chowdari, N.S., Jyothi, K. et al. MCM-41 Anchored Cinchona Alkaloid for Catalytic Asymmetric Dihydroxylation of Olefins: A Clean Protocol for Chiral Diols Using Molecular Oxygen. Catalysis Letters 82, 99–102 (2002). https://doi.org/10.1023/A:1020504511203

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