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Reaction pathway studies of C6 hydrocarbons on palladium model catalysts: effects of hydrogen/hydrocarbon ratio, molecular structure, surface structure and temperature

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Abstract

Reaction pathways of C6 hydrocarbons, such as hydrogenolysis, dehydrogenation, aromatization and dehydrocyclization, have been studied on small surface area palladium model catalysts, including Pd(111) single crystal and polycrystalline palladium foil. These reactions were performed in a batch reactor, at atmospheric pressure and at two different temperatures (573 and 673 K).

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Authors and Affiliations

  1. Department of Chemistry, University of California, Berkeley, CA, 94720-1460, USA

    André L.D. Ramos, Seong Han Kim, Peilin Chen, Jae Hee Song & Gabor A. Somorjai

  2. Materials Sciences Division, Lawrence Berkeley National Laboratory, University of California, Berkeley, CA, 94720, USA

    André L.D. Ramos, Seong Han Kim, Peilin Chen, Jae Hee Song & Gabor A. Somorjai

  3. NUCAT-COPPE/EQ, Universidade Federal do Rio de Janeiro, Caixa Postal 68502, CEP 21941, Rio de Janeiro, RJ, Brazil

    André L.D. Ramos

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  1. André L.D. Ramos
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Ramos, A.L., Kim, S.H., Chen, P. et al. Reaction pathway studies of C6 hydrocarbons on palladium model catalysts: effects of hydrogen/hydrocarbon ratio, molecular structure, surface structure and temperature. Catalysis Letters 66, 5–11 (2000). https://doi.org/10.1023/A:1019091305212

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