Abstract
The passive oxidation behavior of SiC particles has been studied in an electric furnace at atmospheric pressure and in dry air, the weight change due to the transformation from SiC into SiO2 is descibed as a function of exposed temperature and holding time. According to the oxidation data of SiC particles, the oxidation parameters and the degree of oxidation for SiC particles can be controlled. Controllable preoxidation of SiC particles is one of the keys for designing interface and interphase to achieve high performance aluminum composite. Consequently, the evolution of interfacial reaction products in 2014 aluminum alloy composite reinforced with oxidized-SiC particles after extended thermal exposure at elevated temperatures were further characterized by Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM), and X-ray diffraction. While it could act to prevent the interfacial reaction between SiC particles and aluminum alloy, the preoxidation of SiC particles led to the formation of other interfacial reaction products. The observation of the microstructure revealed that at elevated temperatures nano-MgO formed initially on the surface of the oxidized SiC particles and then turned into nano-MgAl2O4 crystal due to the reaction between the SiO2 and aluminum alloy containing Mg. TEM observations indicated that the oxidized layer on SiC particles was uniform and had a good bonding with SiC and aluminum alloy.
Similar content being viewed by others
References
J. A. Costello and R. E. Tressler, J. Amer. Ceram. Soc. 69 (1986) 674.
K. L. Luthra and H. D. Park, ibid. 73 (1990) 1014.
B. Schneider, A. Guette and R. Naslain, J. Mater. Sci. 33 (1998) 535.
V. Laurent, D. Chatain and N. Eustathopoulos, Mater. Sci. Eng. A135 (1991) 89.
H. Ribes, M. Suery, G. 'Esperance and J. G. Legoux, Metall. Trans. A21 (1990) 2489.
W. M. Zhong, G. L'esperance and M. Suery, ibid. A26 (1995) 2637.
Mingyuan Gu, Zhi Mei, Yanping Jin and Zhengan Wu, Scripta Mater. 40 (1999) 985.
R. Y. Lin, “Key Engineering Materials,” edited by G. M. Newaz, H. Neber-Aeschbacher and F. H. Wohlbier, Vols 104–107, 1995, p. 507.
Jae-Chul Lee, J i-Young Byun, Sung-Bae Park and Ho-In Lee, Acta Mater. 46 (1998) 1771.
Jae-Chul Lee, Hyun-Kwang Seok and Ho-In Lee, Materials Research Bulletin, 34 (1999) 35.
Jae-Chul Lee, Sung-Bae Park, Hyun-Kwang Seok, Chang-Seok Oh and Ho-In Lee, Acta Mater. 46 (1998) 2635.
Zhongliang Shi, Tongxiang Fan, Mingyuan Gu, Di Zhang and Renjie Wu, “Advanced Materials and Processing-PRICM 3,” Hawaii, July, edited by T. W. Eagar et al., 1998, p. 401.
Tongxiang Fan, Di Zhang, Zhongliang Shi and Renjie Wu, J. Mater. Sci. 34 (1999) 5175.
J. C. Lee, G. H. Kim and H. I. Lee. Mater. Sci. Tech. 13 (1997) 182.
S. G. Warrier, C. A. Blue and R. Y. Lin, J. Mater. Sci. 28 (1993) 760.
S. G. Warrier and R. Y. Lin,ibid. 28 (1993) 4868.
“CRC Handbook of Chemistry and Physics,” 74th edition (CRC Press, 1992).
J. C. Lee, Jung-Ill Lee and Ho-In Lee, Scripta Mater. 35 (1996) 721.
P. Lu, R. E. Loehman, K. G. Ewsuk and W. G. Fahrenholtz, Acta Mater. 47 (1999) 3099.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Shi, Z., Ochiai, S., Hojo, M. et al. The oxidation of SiC particles and its interfacial characteristics in Al-matrix composite. Journal of Materials Science 36, 2441–2449 (2001). https://doi.org/10.1023/A:1017977931250
Issue Date:
DOI: https://doi.org/10.1023/A:1017977931250