Abstract
Equilibrium partition processes were quantitatively estimated for acidic reagents of the xanthene and triphenylmethane series in the system water–surfactant micelle–stationary phase. An anionic surfactant (sodium dodecyl sulfate) was used as the micelle-forming compound. Partition coefficients were calculated, and the preferential solubilization of reagents in surfactant micelles was demonstrated. Energies of reagent transfer to sodium dodecyl sulfate micelles and their adsorption energies at the stationary phase were calculated.
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Shtykov, S.N., Sumina, E.G. & Tyurina, N.V. Calculation of Partition Coefficients of Organic Reagents in Micellar Thin-Layer Chromatography. Journal of Analytical Chemistry 57, 322–325 (2002). https://doi.org/10.1023/A:1014950314681
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DOI: https://doi.org/10.1023/A:1014950314681