Abstract
An investigation was started aimed at a better understanding of the complex phenomena leading to chemical degradation and morphological deterioration of UHMW polyethylene cups in total hip prostheses. Analysis was performed on retrieved implants which needed revision due to inflammation and pain problems. Preliminary results obtained by parallel XPS and SEM/EDX experiments gave evidence, for the first time, that silicon traces are involved in the process of particle formation and segregation onto the surface of the cups. The extent of modification of the surface chemical composition of cups and the process of particle segregation seem to be correlated to both the implant time and to some particular features of patient (age, activity, style of life, etc.). Investigation on a large number of samples is in progress in order to test this hypothesis. The results obtained so far confirmed the potential of surface spectroscopies (XPS) in biomaterial investigations.
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J. BLACK, H. SHERK, J. BONINI, W. R. ROSTOKER, F. SCHAJOWICZ and J.O. GALANTE, J. Bone Joint Surg. 72 (1990) 126.
M. SPECTOR, S. SHORTKROFF, H. P. HSU, N. LANE, C. B. SLEDGE and T. S. THORNHILL, Clin. Orthop. 261 (1990) 140.
S.M. HOROWITZ, S. B. DOTY, J. M. LANE and A. H. BURSTEIN, J. Bone Joint Surg. 75 (1993) 802.
S. R. GOLDRING, C. R. CLARK and T. M. WRIGHT, J. Bone Joint Surg. 75 (1993) 799.
D.V. CHAVDA and K. L. GARVIN, Clin. Orthop. 303 (1994) 211.
W. A. HODGE, J. P. COLLIER, V. A. SURPRENANT, R. E. JENSEN and H. P. SURPRENANT, Orthop. Rev. 22 (1993) 719.
G.D. HARPER, T. BULL, A. G. COBB and G. BENTLEY, J. Bone Joint Surg. Br. 77 (1995) 557.
D. J. BERRY, L. E. WOLD and J. A. RAND, Clin. Orthop. 293 (1993) 204.
J. L. HAILEY, E. INGHAM, M. STONE, B. M. WROBLEWSKI and J. FISHER, Proc. Inst. Mech. Eng. 210 (1996) 3.
H. C. AMSTUTZ, S. NASSER, R. C. MORE and J. M. KABO, Clin. Orthop. 242 (1989) 104.
V. O. SAIKKO, Acta Orthop. Scand. 64 (1993) 507.
J. M. KABO, J. S. GEBHARD, G. LOREN and H. C. AMSTUTZ, J. Bone Joint Surg. 75 (1993) 254.
A. B. BANKSTON, P.M. FARI S, E. M. KEATING and M. A. RITTER, J. Arthroplasty 8 (1993) 315.
L. SABBATINI and P. G. ZAMBONIN, J. Electron Spectrosc. Relat. Phenom. 81 (1996) 285.
E. DESIMONI and C. MALITESTA, Comput. Enhanced Spectrosc. 3 (1986) 107.
C. MALITESTA, L. SABBATINI, P.G. ZAMBONIN, L. PERALDO BICELLI and S. MAFFI, J. Chem. Soc. Faraday Trans. I 85 (1989) 1685. and accepted 21 June 1999 28
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Giglio, E.D., Motta, A., Quagliarella, L. et al. A combined XPS-SEM/EDX investigation on explanted UHMW polyethylene acetabular cups: possible role of silicon traces in the wear debris. Journal of Materials Science: Materials in Medicine 12, 23–28 (2001). https://doi.org/10.1023/A:1013802716574
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DOI: https://doi.org/10.1023/A:1013802716574