Abstract
Silver electrodeposits prepared from AgNO3 solutions never give compact, smooth plates unless an organic additive, such as tartaric acid (H2A), is used as growth inhibitor. It was shown previously that the relevant chemical entity controlling growth inhibition is the bulk concentration of a neutral associate Ag(HA) formed in the solution between Ag+ and tartaric monoanions HA−. In the present work we extend this investigation to mixed water + dioxane solvent systems where the addition of dioxane, affecting the formation constant of Ag(HA), changes the bulk concentration of this associate. It was found that the associate Ag(HA) also formed in water + dioxane solvent systems is the active component in the solution governing the growth inhibition. On the concentration of this associate most of the structural features of Ag deposits (e.g., the grain size, the superficial roughness and the degree of the preferred orientation <1 1 0>) depend.
Similar content being viewed by others
References
J.C. Evenepoel and R. Winand, Rev. ATB Met. 10 (1970) 132.
C. Digard, G. Maurin and J. Robert, Met. Corros. Ind. 611 (1976) 255.
C. Digard, G. Maurin and J. Robert, Met. Corros. Ind. 613 (1976) 320.
M. Froment, G. Maurin, J. Vereecken and R. Wiart, C.R. Acad. Sci. Paris 271C (1970) 253.
J. Vereecken and R. Winand, Rev. ATB Met. 10 (1970) 147.
G. Fuseya and K. Murata, Trans. Am. Electrochem. Soc. L(1) (1926) 235.
J. Vereecken and R. Winand, J. Electrochem. Soc. 123 (1976) 643.
J. Amblard, M. Froment, C. Georgoulis and G. Papanastasiou, Surf. Technol. 6 (1978) 409.
E.F. Kern, Trans. Amer. Electrochem. Soc. 15 (1909) 441.
V.F. Vladmirova, Sb. Nauchn. Soobshch. Dagest. Gos. Univ., Kafedra Khim. No. 5 (1969) 55.
F.C. Mathers and J.R. Kuebler, Trans. Amer. Electrochem. Soc. 15 (1909) 417.
J. Amblard, M. Froment, C. Georgoulis and G. Papanastasiou, Bull. Soc. Chim. Fr. (1981) I-213.
G. Papanastasiou, 'Study of the Electrodeposition of Silver in the Presence of Tartaric Acid from Aqueous Silver Nitrate Solutions', Treatise for lectureship (Aristotelian University of Thessaloniki, Thessaloniki, 1981).
G. Papanastasiou, D. Jannakoudakis, J. Amblard and M. Froment, J. Appl. Electrochem. 15 (1985) 71.
D.D. Perrin, W.L.F. Armagero and D.R. Perrin, 'Purification of Laboratory Chemicals' (Pergamon Press, Oxford, 1966).
G. Papanastasiou and I. Ziogas, Talanta 36 (1989) 977.
G. Papanastasiou and I. Ziogas, Talanta 42 (1995) 827.
G. Papanastasiou, G. Stalidis and D. Jannakoudakis, Bul. Soc. Chim. Fr. (1984) 255.
R.G. Bates and R.G. Canham, J. Res. Nat. Bur. Stand. 47 (1951) 343.
G. Papanastasiou, I. Ziogas and D. Jannakoudakis, Chimica Chronika, New Series 15 (1986) 147.
H. Fischer and H.F. Heiling, Trans. Inst. Metal Finish. 4th Int. Conf. London 31 (1954) 90.
J. Amblard, M. Froment and G. Maurin, Electrodeposition Surf. Treat. 2 (1974) 205.
J. Amblard, M. Froment and N. Spyrellis, Surf. Technol. 5 (1977) 205.
C.W. Davies, J. Chem. Soc. (1938) 2093.
R.A. Robinson and R.H. Stokes, 'Electrolyte Solutions' (Butter-worths, London, 1968) p. 230.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Zarkadas, G., Stergiou, A. & Papanastasiou, G. Influence of tartaric acid on the electrodeposition of silver from binary water + dioxane AgNO3 solutions. Journal of Applied Electrochemistry 31, 1251–1259 (2001). https://doi.org/10.1023/A:1012780022283
Issue Date:
DOI: https://doi.org/10.1023/A:1012780022283