Abstract
Adsorption isotherms of pyrocatechol, resorcinol, and hydroquinone on hypercrosslinked polystyrene MN-200 are described by the Langmuir equation; distribution coefficients of these compounds are 1500, 550, and 370 mL/g, respectively; breakthrough capacities are 15.3, 11.2, and 11.3 mg/g, respectively. The comparison of hypercrosslinked polystyrene with other sorbents in the efficiency of the dynamic preconcentration of hydroxyphenols demonstrated its advantages. A procedure is proposed for the determination of pyrocatechol, resorcinol, and hydroquinone in water by high-performance liquid chromatography with dynamic on-line preconcentration on a concentrating column instead of the injector loop, which provides the determination of these compounds at concentrations down to 2–3 μg/L. The accuracy of the procedure was verified by the added–found method with a water sample.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
REFERENCES
Wang, L.H. and Luo, Y.-P., Chromatographia, 1999, vol. 49, p. 208.
Penner, N.A. and Nesterenko, P.N., Analyst (Cambridge, U.K.), vol. 125, p. 1249.
Corbett, J.F., Dyes Pigments, 1999, vol. 41, p. 127.
Masque, N., Marce, R.M., and Borrull, F.F., J. Chromatogr., A, 1998, vol. 793, p. 257.
Zhou, J.X. and Wang, E.K., Electroanalysis, 1992, vol. 4, p. 183.
Roush, J.A. and Anderson, M.R., J. Liq. Chromatogr., 1993, vol. 16, p. 3887.
Castilli, M., Puig, D., and Barselo, D., J. Chromatogr. A, 1997, vol. 778, p. 301.
Masque, N., Galia, M., Marce, R.M., and Borrull, F.F., J. Chromatogr. A, 1997, vol. 771, p. 55.
Penner, N.A., Nesterenko, P.N., Ilyin, M.M., et al., Chromatographia, 1999, vol. 50, p. 611.
Streat, M. and Sweetland, L.A., Trans. Inst. Chem. Eng., 1998, vol. 76, p. 115.
Tsyurupa, M.P., Ilyin, M.M., Andreeva, A., and Davankov, V.A., Fresenius' J. Anal. Chem., 1995, vol. 352, p. 672.
Tsyurupa, M.P., Maslova, L., Andreeva, A., et al., React. Funct. Polym., 1995, vol. 25, p. 69.
Khryashchevskii, A.V., Podlovchenko, M.B., Nesterenko, P.N., and Shpigun, O.A., Vestn. Mosk. Univ., Ser. 2: Khim., 1998, vol. 39, p. 196.
Penner, N.A., Nesterenko, P.N., Khryashchevskii, A.V., et al., Mendeleev Commun., 1998, vol. 8, p. 24.
Mijangos, F. and Navarro, A., J. Chem. Eng. Data, 1995, vol. 40, p. 875.
Coquart, V. and Hennion, M.C., J. Chromatogr., 1992, vol. 600, p. 195.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Penner, N.A., Nesterenko, P.N. & Rybalko, M.A. Use of Hypercrosslinked Polystyrene for the Determination of Pyrocatechol, Resorcinol, and Hydroquinone by Reversed-Phase HPLC with Dynamic On-line Preconcentration. Journal of Analytical Chemistry 56, 934–939 (2001). https://doi.org/10.1023/A:1012361428727
Issue Date:
DOI: https://doi.org/10.1023/A:1012361428727