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The crystal and molecular structure of spiro[1-(S)-Br-3-(S)-H-4-(R)-l-(1′ R,2′ S,5′R)-menthyloxy-5-oxo-6-oxa-bicyclo[3.1.0]hexane-2,3′-(R)-(4′-(R)-diphenylmethoxy-5′-l-(1′ R,2′ S,5′ R)-menthyloxy-butyrolactone)]

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Abstract

Crystal structure of C41H53O7Br has been determined by single-crystal X-ray diffraction. The compound crystalline in the orthorhombic space group P212121, with a = 11.264(2), b = 12.058(2), c = 29.337(6) Å, Z = 4. The bond angles of cyclopropane moiety in the molecule are approximate to 60° and agree with theoretic values of the internal angles in a cyclopropane, and two chiral menthyloxy groups are located above and under the whole chiral molecule, respectively. The configuration of the pentacyclic lactone is shown as envelope form.

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Authors and Affiliations

  1. Department of Chemistry, Beijing Normal University, Beijing, 100875, China

    Jin-Nan Zhang, Hui Huang, Qi Li & Qing-Hua Chen

  2. Department of Chemistry, Capital University of Medical Science, Beijing, 100054, China

    Jin-Nan Zhang

  3. Department of Chemistry, Tonghua Teacher's College, Tonghua, 134002, Jilin, China

    Hui Huang

Authors
  1. Jin-Nan Zhang
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  2. Hui Huang
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  3. Qi Li
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  4. Qing-Hua Chen
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Zhang, JN., Huang, H., Li, Q. et al. The crystal and molecular structure of spiro[1-(S)-Br-3-(S)-H-4-(R)-l-(1′ R,2′ S,5′R)-menthyloxy-5-oxo-6-oxa-bicyclo[3.1.0]hexane-2,3′-(R)-(4′-(R)-diphenylmethoxy-5′-l-(1′ R,2′ S,5′ R)-menthyloxy-butyrolactone)]. Journal of Chemical Crystallography 30, 737–741 (2000). https://doi.org/10.1023/A:1012254312765

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