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Thermal Behaviour and Decomposition Kinetics for Two Palladium(II) Complexes with 1-aminopyrene and its Derivative

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Abstract

The thermal decomposition studies for two palladium(II) complexes Pd(apyr)2Cl2 and Pd(pmpa)Cl2 (apyr=1−aminopyrene and pmpa=N−(2−pyridylmethylene)−1−pyrenylamine) were carried out in pure nitrogen using TG-DTG techniques. The non-isothermal kinetic parameters for the two complexes were evaluated employing the method suggested by Málek, Šesták, Koga et al. Based on the above results, thermal behaviour of the complexes were carefully discussed, which showed that not only the parameters value, but also the decomposition pattern and mechanism for complex 1 are different from complex 2.

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Authors and Affiliations

  1. Testing and Analysis Centre, Suzhou University, Suzhou, Jiangsu, 215006, P. R. China

    J. Sun, Z. Lu & Y. Li

  2. Department of Chemistry, Suzhou University, Suzhou, Jiangsu, 215006, P. R. China

    J. Dai

Authors
  1. J. Sun
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  2. Z. Lu
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  3. Y. Li
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  4. J. Dai
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Sun, J., Lu, Z., Li, Y. et al. Thermal Behaviour and Decomposition Kinetics for Two Palladium(II) Complexes with 1-aminopyrene and its Derivative. Journal of Thermal Analysis and Calorimetry 58, 383–391 (1999). https://doi.org/10.1023/A:1010159322866

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  • DOI: https://doi.org/10.1023/A:1010159322866

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