Abstract
The constant potential discharge technique, constant current discharge technique and electrochemical impedance spectroscopy were employed to determine the hydrogen diffusion coefficient in a metal hydride electrode of MlNi3.65Co0.75Mn0.4Al0.2 alloy with various depth of discharge (DOD) at room temperature and with a specific DOD at various temperatures. The results were compared and the advantages and disadvantages of these techniques were also discussed.
Similar content being viewed by others
References
D.-M. Kim, H. Lee, K.-J. Jang and J.-Y. Lee, J. Electrochem. Soc. 145 (1998) 3387.
M.H.J. Van Rijiswick, in A.F. Anderesen and A.J. Maeland (Eds.), 'Hydride for Energy Storage' (Pergamon Press, Oxford, 1978), p. 261.
T. Nishna, H. Ura and I. Uchida, J. Electrochem. Soc. 144 (1997) 1273.
R.C. Bowman, D.M. Gruen and M.H. Mendelsohn, Solid State Commun. 32 (1979) 501.
E. Khodosov, A. Linnik, G. Kobsenko and V. Ivanchenko, in Proceedings of the 2nd international congress on 'Hydrogen in Metals', (Paris, 1977) (Pergamon Press, Oxford, 1977), paper 1D10.
E. Lebsanft, D. Richter and J.M. Topler, Z. Phys. Chem. N.F. 116 (1979) 175.
P. Fischer, A. Furrer, G. Busch and L. Schlapbach, Helv. Phys. Acta. 50 (1977) 421.
G. Zheng, B.N. Popov and R.E. White, J. Electrochem. Soc. 143 (1996) 834.
H. Ura, T. Nishina and I. Uchida, J. Electroanal. Chem. 396 (1995) 169.
C. Iwakura, T. Oura, H. Inoue, M. Matsuoka and Y. Yamamota, J. Electroanal. Chem. 398 (1995) 37.
B.S. Haran, B.N. Popov and R.E. White, J. Power Sources 75 (1998) 56.
P.J. Schneider, in J.F. Lee and A.B. Cambel (Eds.), 'Conduction Heat Transfer' (Addison-Wesley, Cambridge. 1955), p. 246.
G. Zheng, B.N. Popov and R.E. White, J. Electrochem. Soc. 142 (1995) 2695.
T.B. Hunter, P.S. Tyler, W.H. Smyrl and H.S. White, J. Electrochem. Soc. 134 (1987) 2198.
L.M. Gassa, J.R. Vilche, M. Ebert, K. Juttner and W.J. Lorenz, J. Appl. Electrochem. 20 (1990) 677.
T. Pajkossy and L. Nyikos, Electrochimica Acta 34 (1989) 171.
B. Sapoval, Solid State Ionics 23 (1987) 253.
S. Motupally, C.C. Streina and J.W. Weidner J. Electrochem. Soc. 142 (1995) 1401.
P. Yu, B.N. Popov, J.A. Ritter and R.E. White, J. Electrochem. Soc. 146 (1999) 8.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Yuan, X., Xu, N. Comparative study on electrochemical techniques for determination of hydrogen diffusion coefficients in metal hydride electrodes. Journal of Applied Electrochemistry 31, 1033–1039 (2001). https://doi.org/10.1023/A:1017995727600
Issue Date:
DOI: https://doi.org/10.1023/A:1017995727600