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Reaction Kinetics and Catalysis Letters

, Volume 82, Issue 2, pp 333–337 | Cite as

Synthesis of acetone oxime through acetone ammoximation over TS-1

  • Xinhua Liang
  • Zhentao Mi
  • Yaquan Wang
  • Li Wang
  • Xiangwen Zhang
Article

Abstract

The ammoximation of acetone to acetone oxime with 30 wt.% hydrogen peroxide over TS-1 has been studied. The conversion of acetone and the selectivity to acetone oxime can reach 99% and 94%, respectively. The by-products are the corresponding hydrazone, imine and small amounts of unidentified compounds. The influence of various parameters such as solvent, temperature, amounts of catalyst and the NH3 to acetone molar ratio were investigated.

hydrogen peroxide ammoximation TS-1 acetone Acetone oxime 

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Copyright information

© Kluwer Academic Publisher/Akadémiai Kiadó 2004

Authors and Affiliations

  • Xinhua Liang
    • 1
  • Zhentao Mi
    • 1
  • Yaquan Wang
    • 1
  • Li Wang
    • 1
  • Xiangwen Zhang
    • 1
  1. 1.School of Chemical Engineering &TechnologyTianjin UniversityTianjinP. R. China

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