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Russian Journal of Organic Chemistry

, Volume 40, Issue 4, pp 482–488 | Cite as

Polybromocyclopentadienes in Diels–Alder Reactions. Reactions of Hexabromo- and 5,5-Dimethoxytetrabromo-1,3-cyclopentadienes with para-Substituted Allyl Benzoates

  • A. M. Magerramov
  • A. M. Mustafaev
  • G. Kh. Velieva
  • S. D. Murshudova
  • M. A. Allakhverdiev
Article

Abstract

The Diels–Alder reaction of hexabromo- and 5,5-dimethoxytetrabromo-1,3-cyclopentadienes with para-substituted allyl benzoates occurs with high stereoselectivity, yielding the corresponding endo adducts. The kinetics of this reaction were studied, and its activation parameters were determined. The reaction is favored by the presence of both electron-donor and electron-acceptor substituents in the aromatic ring. The diene–dienophile system was assumed to react according to the “neutral” pattern.

Keywords

Organic Chemistry Adduct Aromatic Ring Diene Allyl 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© MAIK “Nauka/Interperiodica” 2004

Authors and Affiliations

  • A. M. Magerramov
    • 1
  • A. M. Mustafaev
    • 1
  • G. Kh. Velieva
    • 1
  • S. D. Murshudova
    • 1
  • M. A. Allakhverdiev
    • 1
  1. 1.Baku State UniversityBakuAzerbaidjan

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