Russian Journal of Organic Chemistry

, Volume 40, Issue 3, pp 431–433 | Cite as

First Example of 1,3-Dipolar Cycloaddition of Carbonyl Ylides to Cyclopropenes

  • A. P. Molchanov
  • V. V. Diev
  • J. Kopf
  • R. R. Kostikov
Article

Abstract

Carbonyl ylide generated from 1-diazo-5-phenylpentane-2,5-dione in the presence of Rh2(OAc)4 reacts with 3-substituted cyclopropenes following the 1,3-dipolar cycloaddition pattern to afford substituted 9-oxatricyclo[3.3.1.02,4]nonan-6-ones.

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Copyright information

© MAIK “Nauka/Interperiodica” 2004

Authors and Affiliations

  • A. P. Molchanov
    • 1
  • V. V. Diev
    • 1
  • J. Kopf
    • 2
  • R. R. Kostikov
    • 1
  1. 1.St. Petersburg State UniversitySt. PetersburgRussia
  2. 2.Institut für anorganische ChemieHamburgGermany

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