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Russian Journal of Organic Chemistry

, Volume 40, Issue 3, pp 431–433 | Cite as

First Example of 1,3-Dipolar Cycloaddition of Carbonyl Ylides to Cyclopropenes

  • A. P. Molchanov
  • V. V. Diev
  • J. Kopf
  • R. R. Kostikov
Article

Abstract

Carbonyl ylide generated from 1-diazo-5-phenylpentane-2,5-dione in the presence of Rh2(OAc)4 reacts with 3-substituted cyclopropenes following the 1,3-dipolar cycloaddition pattern to afford substituted 9-oxatricyclo[3.3.1.02,4]nonan-6-ones.

Keywords

Organic Chemistry Carbonyl Dione Cyclopropenes Carbonyl Ylide 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© MAIK “Nauka/Interperiodica” 2004

Authors and Affiliations

  • A. P. Molchanov
    • 1
  • V. V. Diev
    • 1
  • J. Kopf
    • 2
  • R. R. Kostikov
    • 1
  1. 1.St. Petersburg State UniversitySt. PetersburgRussia
  2. 2.Institut für anorganische ChemieHamburgGermany

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