Journal of Radioanalytical and Nuclear Chemistry

, Volume 261, Issue 3, pp 609–617 | Cite as

Evaluation of a single collector, double focusing sector field inductively coupled plasma mass spectrometer for the determination of U and Pu concentrations and isotopic compositions at trace level

  • N. Baglan
  • P. Hemet
  • F. Pointurier
  • R. Chiappini


This work explores the performance of the “Axiom”, a double focusing sector field ICP-MS (ICP-SFMS) in the determination of actinide concentration and isotopic ratio at trace level. On the actinide mass range the performances observed are characterized by high sensitivity, around 2.8·106 cps·µg−1·l, and low background, below 0.3 cps. Therefore, the absolute instrumental detection limit is approximately 0.05 fg for Pu isotopes. Furthermore, the 235U/238U ratio for a 0.5 µg·l−1 U500 isotopic standard could now be measured using the ICP-SFMS with a relative standard deviation less than 0.1%. Moreover, the accuracy of the measured ratio was demonstrated at low concentration with the target value remaining within experimental uncertainty limits.


Uranium 234U Instrumental Detection Limit 238U Ratio Minor Isotope 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.


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Copyright information

© Kluwer Academic Publisher/Akadémiai Kiadó 2004

Authors and Affiliations

  • N. Baglan
    • 1
  • P. Hemet
    • 1
  • F. Pointurier
    • 1
  • R. Chiappini
    • 1
  1. 1.CEA/DIF/DASE/SRCE - BP 12 -France

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