Supramolecular Polymeric Macrocyclic Receptors – Hybrid Carrier versus Channel Transporters in Bulk Liquid Membranes

  • Mihail Barboiu
Article

Abstract

The synthesis of heteroditopic macrocyclic ureido-receptors is described. NMR studies show the formation of self-organized oligomeric superstructures. Membrane transport experiments show a direct relation between the self-assembling and the transport properties of these molecular information transfer devices. The self-organization of these receptors may provide the first evidence for the possible hybrid transport carrier versus channel mechanisms in liquid membranes.

crown compounds dynamic self-assembly liquid membranes macrocyclic carrier 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    J.-M. Lehn: Supramolecular Chemistry-Concepts and Perspectives, VCH, Weinheim (1995), p. 69.Google Scholar
  2. 2.
    J.-M. Lehn: Chem. Eur. J. 5, 2455 (1999).Google Scholar
  3. 3.
    G.W. Gokel and A. Mukhopadhyay: Chem. Soc. Rev. 30, 274, (2001).Google Scholar
  4. 4.
    N. Voyer: Top. Curr. Chem. 184, 1 (1996).Google Scholar
  5. 5.
    D.T. Bong, T.D. Clark, J.R. Granja, and M.R. Ghadiri: Angew. Chem., Int. Ed. Engl. 40, 988 (2001).Google Scholar
  6. 6.
    S. Mantile: Chem. Soc. Rev. 30, 158 (2001).Google Scholar
  7. 7.
    J.-M. Lehn: in A. Cifai (ed.), Supramolecular Polymers, Dekker, New York, (2000), p. 615.Google Scholar
  8. 8.
    J.-M. Lehn: Polym. Int. 51, 825 (2002).Google Scholar
  9. 9.
    M. Barboiu, G. Vaughan, and A. van der Lee: Org. Lett. 5, 3073 (2003).Google Scholar
  10. 10.
    X. Cheng, Q. Gao, R.D. Smith, E.E. Simanek, M. Mammen, and G.M. Whitsides: J. Org. Chem. 61, 2201 (1996).Google Scholar
  11. 11.
    L.A. LaPlanche, H.B. Thompson, and M.T. Rogers: J. Phys. Chem. 69, 1482 (1965).Google Scholar
  12. 12.
    M. Akiama and T. Ohtani: Spectrochim. Acta Part A 50A, 317 (1994).Google Scholar
  13. 13.
    M. de Loos, J. van Esch, R.M. Kellog, and B.L. Feringa: Angew. Chem. Int. Ed. Engl. 40, 613 (2001).Google Scholar
  14. 14.
    L.A.J. Chrisstoffels, F. de Jong, and D.N. Reinhoudt: Chem. Eur. J. 6, 1376 (2000).Google Scholar
  15. 15.
    L.A.J. Chrisstoffels: Ph.D. Thesis, University of Twente, 1998.Google Scholar
  16. 16.
    M.M.G. Antonisse and D.N. Reinhoudt: Chem. Commun. 443 (1998).Google Scholar
  17. 17.
    M.C. Etter: Acc. Chem. Res. 23, 120 (1990).Google Scholar

Copyright information

© Kluwer Academic Publishers 2004

Authors and Affiliations

  • Mihail Barboiu
    • 1
  1. 1.Institut Européen des Membranes – IEM-UMR CNRS 5635MontpellierFrance

Personalised recommendations