Catalysis Letters

, Volume 91, Issue 3, pp 193–198

Photocatalytic Water Splitting over La2Ti2O7 Synthesized by the Polymerizable Complex Method

  • Hyun Gyu Kim
  • Dong Won Hwang
  • Sang Won Bae
  • Jong Hyeon Jung
  • Jae Sung Lee
Article

DOI: 10.1023/B:CATL.0000007154.30343.23

Cite this article as:
Kim, H.G., Hwang, D.W., Bae, S.W. et al. Catalysis Letters (2003) 91: 193. doi:10.1023/B:CATL.0000007154.30343.23

Abstract

Highly donor-doped (110) layered perovskite materials, La2Ti2O7, with high surface areas were synthesized by the polymerizable complex (PC) method. Relative to La2Ti2O7 prepared by the solid state reaction (SSR) method, PC catalysts showed higher surface areas, crystallization at lower temperatures, higher phase purity, more uniform morphology and better-distributed nickel on the outer surface of La2Ti2O7. All these factors led to higher photocatalytic activity for overall water splitting under UV irradiation. The quantum yield of the reaction over La2Ti2O7 prepared by the PC method was as high as 27%, which was about twofold greater than that over La2Ti2O7 prepared by the SSR method.

La2Ti2O7 polymerizable complex method photocatalytic activity water splitting 

Copyright information

© Plenum Publishing Corporation 2003

Authors and Affiliations

  • Hyun Gyu Kim
    • 1
  • Dong Won Hwang
    • 1
  • Sang Won Bae
    • 1
  • Jong Hyeon Jung
    • 2
  • Jae Sung Lee
    • 1
  1. 1.Department of Chemical Engineering/Institute of Environmental and Energy TechnologyPohang University of Science and Technology (POSTECH)PohangRepublic of Korea
  2. 2.Division of Biotechnology and Health EngineeringSorabol CollegeKorea

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