Theoretical Foundations of Chemical Engineering

, Volume 37, Issue 5, pp 429–438 | Cite as

Carbon Nanofibers: A New Ultrahigh-Strength Material for Chemical Technology

  • V. Z. Mordkovich


Carbon nanofibers are described as a new ultrahigh-strength material, which is superior to both ordinary carbon fibers and other high-strength materials. The place occupied by nanofibers in the classification of carbon materials is shown, and an analysis is made of the relationship between the structure of a fiber and its useful properties, in particular, the strength and tensile modulus. Studies on the synthesis of nanofibers are reviewed. It is shown that the practically important problem of producing nanofibers of maximum possible length must be solved by controlling the temperature conditions of the reaction. The prospects for introducing nanofibers into the market of high-strength and heat-resistant materials are analyzed. The most likely prospect seems to be the partial replacement of polyacrylonitrile-based fibers by nanofibers, first and foremost, in the fields where the requirements for high strength are particularly stringent due to safety reasons.


Carbon Fiber Carbon Material Chemical Technology Partial Replacement Carbon Nanofibers 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.


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  1. 1.
    Inagaki, M., New Carbons: Control of Structure and Functions, Oxford: Elsevier, Sci., 2002.Google Scholar
  2. 2.
    Sciences of Carbon Materials Marsh, H. Ed., Alicante: Univ. di Alicante, 2000.Google Scholar
  3. 3.
    Baker, R.T.K. and Harris, P.S., The Formation of Filamentous Carbon, Chemistry and Physics of Carbon Walker, P.L. and Thrower, P.A., Eds., New York: Marcel Dekker, 1978, p. 83.Google Scholar
  4. 4.
    Carbon Nanotubes, Endo, M., Ed., Oxford: Pergamon, 1996.Google Scholar
  5. 5.
    Carbon Nanotubes: Preparation and Properties, Ebbesen, T.W., Ed., New York: CRC, 1997.Google Scholar
  6. 6.
    Dresselhaus, M.S., Dresselhaus, G., and Eklund, P.C., {tiScience of Fullerenes and Carbon Nanotubes}, London: Academic, 1996.Google Scholar
  7. 7.
    Eletskii, A.V., Carbon Nanotubes, Usp. Fiz. Nauk {dy1997}, vol. 167, no. 9, p. 945.Google Scholar
  8. 8.
    Rakov, E.G., Nanotubes of Inorganic Substances, Zh. Neorg. Khim., 1999, vol. 44, no. 11, p. 1827.Google Scholar
  9. 9.
    Zelenskii, E.S., Kuperman, A.M., Gorbatkina, Yu.A., et al., Reinforced Plastics: Modern Construction Materials, {tiRoss. Khim. Zh.}, 2001, vol. 44, no. 2, p. 56.Google Scholar
  10. 10.
    Guigon, M., Oberlin, A., and Desarmot, G., Microtexture and Structure of Some High-Modulus, PAN-Base Carbon Fibers, Fibre Sci. Tech., 1984, vol. 20, p. 177.Google Scholar
  11. 11.
    Tibbetts, G.G. and Beetz, C.P., Mechanical Properties of Vapor-Grown Carbon Fibers, J. Phys. D: Appl. Phys., 1987, vol. 20, p. 292.Google Scholar
  12. 12.
    Oberlin, A., Endo, M., and Koyama, T., Filamentous Growth of Carbon through Benzene Decomposition, {tiJ. Cryst. Growth}, 1976, vol. 32, p. 335.Google Scholar
  13. 13.
    Endo, M., Vapor-Grown Carbon Fibers, Ph.D. Thesis, Nagoya: Nagoya Univ., 1978.Google Scholar
  14. 14.
    Endo, M. and Sikata, M., Tanso faiba (Carbon Fibers), {tiOio Butsuri}, 1985, vol. 54, p. 507.Google Scholar
  15. 15.
    Endo, M., Oberlin, A., and Koyama, T., Structure and Growth Mechanism of Vapor-Grown Carbon Fibers, {tiJpn. J. Appl. Phys., Part 1}, 1977, vol. 16, p. 1519.Google Scholar
  16. 16.
    Katsuki, H., Matsunaga, K., Egashira, M., and Kawasumi, S., Formation of Carbon Fibers from Naphthalene on Some Sulfur-Containing Substrates, Carbon, 1981, vol. 9, p. 148.Google Scholar
  17. 17.
    Ishioka, M., Okada, T., and Matsubara, K., Formation of Vapor-Grown Carbon Fibers in Carbon Monoxide‐Carbon Dioxide‐Hydrogen Mixtures: I. Influence of Carrier Gas Composition, Carbon, 1992, vol. 30, p. 859.Google Scholar
  18. 18.
    Ishioka, M., Okada, T., and Matsubara, K., Formation of Vapor-Grown Carbon Fibers in Carbon Monoxide‐Carbon Dioxide‐Hydrogen Mixtures: II. Influence of Catalyst, {tiCarbon}, 1992, vol. 30, p. 975.Google Scholar
  19. 19.
    Tibbetts, G.G., Lengths of Carbon Fibers Grown from Iron Catalyst Particles in Natural Gas, J. Cryst. Growth, 1985, vol. 73, p. 431.Google Scholar
  20. 20.
    Egashira, M., Katsuki, H., Khayasi, K., and Kawasumi, S., Sekubai-no tanso faiba (Catalytic Carbon Fibers), Sekiyu Gakkai Si, 1983, vol. 26, p. 247.Google Scholar
  21. 21.
    Motojima, S., Hasegawa, I., Kagiya, S., et al., Vapor Phase Preparation of Micro-Coiled Carbon Fibers by Metal Powder Catalyzed Pyrolysis of Acetylene Containing a Small Amount of Phosphorus Impurity, Carbon, 1995, vol. 33, p. 1167.Google Scholar
  22. 22.
    Motojima, S., Ivanaga, H., and Varadan, V.K., Kabon maikuro koiru (Carbon Microcoils), Homen, 1998, vol. 36, p. 140.Google Scholar
  23. 23.
    Soneda, Y. and Inagaki, M., Formation and Graphitization of Vapor-Grown Carbon Fibers, Z. Anorg. Allg. Chem, 1992, vol. 610, p. 157.Google Scholar
  24. 24.
    Imamutdinov, I. and Perekhodtsev, G., Dirty Glass Effect, Ekspert, October 8, 2001, no. 37.Google Scholar
  25. 25.
    Seible, F., Priestley, N., and Innamorato, D., Earthquake Retrofit of Bridge Columns with Continuous Carbon Fiber Jackets. Report No. ACTT-95/08, Report to Caltrans, Division of Structures, Prepared under the ARPA/TRP Program Agreement No. MDA 972-94-3-0030, San Diego: Univ. Calif., 1998.Google Scholar

Copyright information

© MAIK “Nauka/Interperiodica” 2003

Authors and Affiliations

  • V. Z. Mordkovich
    • 1
  1. 1.International Center for Materials ResearchKawasaki-ku, KawasakiJapan

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