Journal of Nanoparticle Research

, Volume 5, Issue 3, pp 389–393

Nanometric Antimony Powder Synthesis by Activated Alkaline Hydride Reduction of Antimony Pentachloride

  • A. Dailly
  • R. Schneider
  • D. Billaud
  • Y. Fort
  • J. Ghanbaja
Article

DOI: 10.1023/A:1025529305575

Cite this article as:
Dailly, A., Schneider, R., Billaud, D. et al. Journal of Nanoparticle Research (2003) 5: 389. doi:10.1023/A:1025529305575

Abstract

A novel chemical reduction method using an activated alkaline hydride (LiH or NaH-t-BuONa) in tetrahydrofuran solvent has been applied to antimony salt reduction. X-ray diffraction and transmission electron microscopy studies have been carried out to characterize the morphology and structure of the materials. Alkali hydride nature influence has been proved. In both cases the process allows to prepare antimony particles in nanometer range from few nanometers to about 20nm which could be used as anodic materials for lithium–ion batteries. With lithium hydride well-crystallized particles inclined to agglomeration were observed whereas finely dispersed amorphous particles were pointing out after activated sodium hydride reduction.

activated hydride reduction nanosized antimony particles nanoparticles anodic material lithium-ion batteries 

Copyright information

© Kluwer Academic Publishers 2003

Authors and Affiliations

  • A. Dailly
    • 1
  • R. Schneider
    • 2
  • D. Billaud
    • 1
  • Y. Fort
    • 2
  • J. Ghanbaja
    • 3
  1. 1.Laboratoire de Chimie du Solide MinéralUMR 7555France
  2. 2.Synthèse organique et Réactivité, UMR 7565France
  3. 3.Service Commun de Microscopie Electronique par Transmission, UHP-Nancy IVandoeuvre les Nancy CedexFrance

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