Hyperfine Interactions

, Volume 144, Issue 1–4, pp 307–323 | Cite as

Photoswitching of Nitroprussides

  • V. Rusanov
  • Sv. Stankov
  • A. X. Trautwein


For 25 years the two metastable electronic states (SI and SII), accessible in the nitroprusside anion [Fe(CN)5NO]2− (NP) by irradiation with blue polarized light, have been the subject of intense investigations from several research groups. This review article summarizes the most important experimental results in the field of photochromatic effects investigated by nuclear resonant methods. The experimentally determined data have been compared with the results derived from density functional theory calculations. The majority of results convincingly indicates: (i) the SI state is represented by the isonitrosyl conformation (Fe-O-N) of the (NO+)-group and (ii) the SII state is represented by a dynamic conformation, in which a bending vibration of Fe-O-N as well as a rotation of the (NO+)-group around the main molecular axis simultaneously occur. A possible formation of a new third metastable state observed in rare-earth nitroprussides, which is stable at room temperature, will be discussed.

photoswitching optical bistability structural changes density-functional theory nuclear resonant methods 


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  1. 1.
    Hauser, U., Oestreich, V. and Rohrweck, H. D., Z. Phys. A 280 (1977), 17, 125; 284 (1978), 9.CrossRefADSGoogle Scholar
  2. 2.
    Spijkerman, J. J., Ruegg, F. C. and DeVoe, J. R., Tech. Rep. Ser. I. A. E. A. 50 (1966), 254.Google Scholar
  3. 3.
    Bottomly, F. and White, P. S., Acta Crystallogr. B 35 (1979), 2193.CrossRefGoogle Scholar
  4. 4.
    Gómez, J. A. and Guenzburger, D., Chem. Phys. 235 (2000), 73.CrossRefGoogle Scholar
  5. 5.
    Grant, R. W., Housley, R. M. and Gonser, U., Phys. Rev. 178 (1969), 523.CrossRefADSGoogle Scholar
  6. 6.
    Woike, Th., Krasser, W., Zöllner, H., Kirchner, W. and Haussühl, S., Z. Phys. D 25 (1993), 351.CrossRefADSGoogle Scholar
  7. 7.
    Woike, Th., Kirchner, W., Schetter, G., Barthel, Th., Kim, H. and Haussühl, S., Opt. Commun. 106 (1994), 6.CrossRefADSGoogle Scholar
  8. 8.
    Haussühl, S., Schetter, G. and Woike, Th., Opt. Commun. 114 (1995), 219.CrossRefADSGoogle Scholar
  9. 9.
    Zöllner, H., Woike, Th., Krasser, W. and Haussühl, S., Z. Kristallogr. 188 (1989), 139.CrossRefGoogle Scholar
  10. 10.
    Woike, Th., Kirchner, W., Kim, H., Haussühl, S., Rusanov, V., Angelov, V., Ormandjiev, S., Bonchev, Ts. and Schroeder, A. N. F., Hyp. Interact. 77 (1993), 265.CrossRefADSGoogle Scholar
  11. 11.
    Rusanov, V., Woike, Th., Kim, H., Angelov, V., Bonchev, Ts. and Haussühl, S., Solid State Commun. 126 (2003), 457.CrossRefADSGoogle Scholar
  12. 12.
    Rusanov, V., Angelov, V., Angelova, J., Bonchev, Ts., Woike, Th., Kim, H. and Haussühl, S., J. Sol. State Chem. 123 (1996), 39.CrossRefADSGoogle Scholar
  13. 13.
    Hauser, U., Klimm, W., Reder, L., Schmitz, T., Wessel, M. and Zellmer, H., Phys. Lett. A 144 (1990), 39.CrossRefADSGoogle Scholar
  14. 14.
    Woike, Th., Zöllner, H., Krasser, W. and Haussühl, S., Solid State Commun. 73 (1990), 149.CrossRefADSGoogle Scholar
  15. 15.
    Guida, J. A., Piro, O. E. and Aymonino, P. J., Inorg. Chem. 34 (1995), 4113.CrossRefGoogle Scholar
  16. 16.
    Coppens, P., Fomitchev, D., Carducci, M. and Culp, K., J. Chem. Soc., Dalton Trans. (1998), 865.Google Scholar
  17. 17.
    Rusanov, V., Winkler, H., Ober, C. and Trautwein, A. X., Eur. Phys. J. B 12 (1999), 191.CrossRefADSGoogle Scholar
  18. 18.
    Retzlaff, C., Krumbe, W., Dörffer, M. and Haussühl, S., Z. Kristallog. 189 (1989), 141.CrossRefGoogle Scholar
  19. 19.
    Rusanov, V., Stankov, Sv., Angelov, V., Koop, N., Winkler, H. and Trautwein, A. X., Nucl. Instr. Meth. B 207 (2003), 205.CrossRefADSGoogle Scholar
  20. 20.
    Güdel, H. U., Chem. Phys. Lett. 175 (1990), 262.CrossRefADSGoogle Scholar
  21. 21.
    Rüdlinger, M., Schefer, J., Chevrier, G., Furer, N., Güdel, H. U., Haussühl, S., Heger, G., Schweiss, P., Vogt, Th., Woike, Th. and Zöllner, H., Z. Phys. B 83 (1991), 125.CrossRefADSGoogle Scholar
  22. 22.
    Schefer, J., Woike, Th., Haussühl, S. and Fernandes-Dias, M., Z. Kristallogr. 212 (1997), 29.CrossRefGoogle Scholar
  23. 23.
    Carducci, M. D., Pressprich, M. R. and Coppens, P., J. Am. Chem. Soc. 119 (1997), 2669.CrossRefGoogle Scholar
  24. 24.
    Schefer, J., Woike, Th., Imlau, M. and Delley, B., Eur. Phys. J. B 3 (1998), 349.CrossRefADSGoogle Scholar
  25. 25.
    Delley, B., Schefer, J., Woike, Th., J. Chem. Phys. 107 (1997), 10067.CrossRefADSGoogle Scholar
  26. 26.
    Blaha, P., Schwarz, K., Faber, W. and Luitz, J., Hyp. Interact. 126 (2000), 389.CrossRefADSGoogle Scholar
  27. 27.
    Rusanov, V., Grünsteudel, H., Paulsen, H., Winkler, H., Meyer-Klaucke, W. and Trautwein, A. X., Hyp. Interact. 126 (2000), 159.CrossRefADSGoogle Scholar
  28. 28.
    Woike, Th., Imlau, M., Angelov, V., Schefer, J. and Dellej, B., Phys. Rev. B 61 (2000), 12249.CrossRefADSGoogle Scholar
  29. 29.
    Timmermann, A., Thesis, Ph. D., Universität zu Köln, 1981.Google Scholar
  30. 30.
    Oosterhuis, W. T. and Lang, G., J. Chem. Phys. 50 (1969), 4381.CrossRefADSGoogle Scholar
  31. 31.
    Rusanov, V., Stankov, Sv., Angelov, V. and Schünemann, V., Nucl. Instr. Meth. B 170 (2000), 443.CrossRefADSGoogle Scholar
  32. 32.
    Stankov, Sv., Rusanov, V., Angelov, V., Haussühl, S. and Trautwein, A. X., Hyp. Interact. 141/142 (2002), 223.CrossRefADSGoogle Scholar
  33. 33.
    Morioka, Y., Takeda, S., Tomizawa, H., Miki, E., Chem. Phys. Lett. 292 (1998), 625.CrossRefADSGoogle Scholar
  34. 34.
    ChaĆon Villalba, M. E., Güida, J. A., Varetti, E. L. and Aymonino, P. J., Spectrochim. Acta A 57 (2001), 367.CrossRefGoogle Scholar
  35. 35.
    Paulsen, H., Rusanov, V., Benda, R., Herta, C., Schünemann, V., Janiak, C., Dorn, T., Chumakov, A., Winkler, H. and Trautwein, A. X., J. Am. Chem. Soc. 124 (2002), 3007.CrossRefGoogle Scholar
  36. 36.
    Coppens, P., Novozhilova, I. and Kovalevsky, A., Chem. Rev. 102 (2002), 861.CrossRefGoogle Scholar
  37. 37.
    Paulsen, H., personal communication.Google Scholar
  38. 38.
    Sato, O., Iyoda, T., Fujishima, A. and Hashimoto, K., Science 272 (1996), 704.ADSGoogle Scholar
  39. 39.
    Verdaguer, M., Science 272 (1996), 698.ADSGoogle Scholar
  40. 40.
    Morioka, Y., Hisamitsu, T., Inoue, H., Yoshioka, N., Tomizawa, H. and Miki, E., Bull. Chem. Soc. Jpn. 71 (1998), 837.CrossRefGoogle Scholar
  41. 41.
    Inoue, H., Yoshioka, N. and Morioka, Y., Hyp. Interact. (C) 3 (1998), 113.Google Scholar
  42. 42.
    Gütlich, P., Garsia, Y., Woike, Th., Coord. Chem. Rev. 219 (2001), 839.CrossRefGoogle Scholar

Copyright information

© Kluwer Academic Publishers 2002

Authors and Affiliations

  • V. Rusanov
    • 1
    • 2
  • Sv. Stankov
    • 1
    • 2
  • A. X. Trautwein
    • 2
  1. 1.Department of Atomic PhysicsUniversity of Sofia, Faculty of PhysicsSofiaBulgaria
  2. 2.Institut für PhysikUniversität zu LübeckLübeckGermany

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