, Volume 64, Issue 2, pp 165–178 | Cite as

Long term records of riverine dissolved organic matter

  • Fred Worrall
  • Tim Burt
  • Rosalyn Shedden


This presents the longest, consistent records of dissolved organic carbon in rivers ever published. This study presents long-term records of organic matter as indicated by water colour that were constructed for three catchments in Northern England for as far back as 1962. Observations show that there have been large increases in DOC concentrations over the period of study with in one case a doubling of the concentration over a period of 29 years. However, in one of the catchments no significant change was observed over a 31-year period. All catchments show common inter-annual control on carbon release in response to droughts, but no step increases in DOC concentrations were observed in response to such perturbations with pre-drought levels being restored within a period 3–4 years. Observed increasing trends do not correlate with changes in river discharge, pH, alkalinity or rainfall, but do coincide with increasing average summer temperatures in the region. The times series of DOC concentration over the period of the record appears stationary, but the distribution of daily values suggests a change in sources of colour over the increasing trend. The evidence supports a view that increases in carbon release are in equilibrium with temperature increases accentuated by land-use factors.

Climate change DOC Land use Rivers Trends 


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  1. Aitkenhead J.A., Hope D. and Billet M.F. 1999. The relationship between dissolved organic carbon in stream water and soil organic carbon pools at differential spatial scales. Hydrol. Processes 13: 1289–1302.Google Scholar
  2. Asite E. and Klavins M. 1998. Assessment of the changes of COD and color in rivers of Latvia during the last twenty years. Environ. Int. 24: 637–643.Google Scholar
  3. Borken W., Xu Y.J., Brumme R. and Lamersdorf N. 1999. A climate change scenario for carbon dioxide and dissolved organic carbon flux from a temperate forest soil: drought and rewetting effects. Soil Sci. Soc. Amer. J. 63: 1848–1855.Google Scholar
  4. Broberg O. 1990. Elemental sulphur and sodium sulphate treatment of catchments in the Gardsjon area, southwest Sweden. Effects on phosphorus, nitrogen and DOC. In: Mason B.J. (ed.), The Surface Water Acidification Programme. Cambridge University Press, Cambridge, pp. 193–198.Google Scholar
  5. Burt T.P., Adamson J.K. and Lane A.M.J. 1998. Long-term rainfall and streamflow records for north central England: putting the Environmental Change Network site at Moor House, Upper Teesdale, in context. Hydrol. Sci. J. 43: 775–787.Google Scholar
  6. Cannell M.G.R., Dewar R.C. and Pyatt D.G. 1993. Conifer plantations on drained peatlands in Britain: a net gain or loss of carbon. Forestry 66: 353–369.Google Scholar
  7. Cannell M.G.R., Milne R., Hargreaves K.J., Brown T.A.W., Cruikshank M.M., Bradley R.I. et al. 1999. National inventory of terrestrial carbon sources and sinks: the UK experience. Climate Change 42: 505–530.Google Scholar
  8. Clair T.A., Ehrman J.M. and Higuchi K. 1999. Changes in freshwater carbon exports from canadian terrestrail basins to lakes and estuaries under a 2 × CO2 atmospheric scenario. Global Biogeochemical Cycles 13: 1091–1097.Google Scholar
  9. Clymo R.S. 1983. Peat. In: Gore A.J.P. (ed.), Mires, Swamp, Bog, Fen and Moor. Ecosystems of the World 4A. Elsevier, Amsterdam, pp. 159–224.Google Scholar
  10. Dixon R.K. and Turner D.P. 1991. The global carbon cycle and climate change: responses and feedbacks from below ground systems. Environ. Pollution 73: 245–262.Google Scholar
  11. Eatherall A., Naden P.S. and Cooper D.M. 1998. Simulating carbon flux to the estuary: the first step. Sci. Tot. Environ. 210/211: 519–533.Google Scholar
  12. Eatherall A., Warwick M.S. and Tolchard S. 2000. Identifying sources of dissolved organic carbon on the River Swale, Yorkshire. Sci. Tot. Environ. 251/252: 171–190.Google Scholar
  13. Freeman C., Ostle N. and Kang H. 2001a. An enzymic' latch' on a global carbon store – a shortage of oxygen locks up carbon in peatlands by restraining a single ezyme. Nature 409: 149.Google Scholar
  14. Freeman C., Evans C.D., Montieth D.T., Reynolds B. and Fenner N. 2001b. Export of organic carbon from peat soils. Nature 412: 785.Google Scholar
  15. Gorham E. 1991. Northern peatlands role in the carbon cycle and probable responses to climate warming. Ecol. Applications 1: 182–195.Google Scholar
  16. Grieve I.C. 1990a. Variations in the chemical composition of the soil solution over a four year period at an upland site in southwest Scotland. Geoderma 46: 351–362.Google Scholar
  17. Grieve I.C. 1990b. Soil and soil solution chemical composition at three sites within the Loch Dee catchment, SW Scotland. J. Soil Sci. 41: 269–277.Google Scholar
  18. Hall R.J., Driscoll C.T. and Likens G.E. 1987. Importance of hydrogen ions and aluminium in regulating the structure and function of stream ecosystems: an experimental test. Fresh. Biol. 18: 17–43.Google Scholar
  19. HMSO 1994. Climate Change – United Kingdom's Report Under the Framework Convention on Climate Change. HMSO, London.Google Scholar
  20. Holden J. 2000. Runoff production in blanket peat covered catchments. PhD Dissertation, University of Durham.Google Scholar
  21. Hongve D.A.G. and Åkesson G. 1996. Spectrophotometric determination of water colour in Hazen units. Water Research 30: 2771–2775.Google Scholar
  22. Hope D., Billet M.F. and Cresser M.S. 1994. A review of the export of carbon in river water: fluxes and processes. Hydrol. processes 84: 301–324.Google Scholar
  23. Hope D., Billet M.F., Mile R. and Brown T.A.W. 1997. Exports of organic carbon in British rivers. Hydrol. Processes 11: 325–344.Google Scholar
  24. Kaiser K., Guggenberger G., Haumeier L. and Zech W. 2001. Seasonal variations in the chemical composition of dissolved organic matter in organic forest floor layer leachates of old growth scots pine (Pinus sylvestins) and European beech (Gagus sylvatica) stands in north eastern Bavaria, Germany. Biogeochemistry 55: 103–143.Google Scholar
  25. Kullberg A. and Petersen R.C. 1987. Dissolved Organic carbon, seston and macroinvertebrate drift in an acidified and limed humic stream. Fresh. Biol. 17: 553–564.Google Scholar
  26. Littlewood I.G. 1992. Estimating constituent loads in rivers: a review. Institute of Hydrology, rep. 117. Institute of Hydrology, Wallingford, UK.Google Scholar
  27. Miller J.D., Adamson J.K. and Hirst D. 2001. Trends in stream water quality in environmental change network upland catchments: the first 5 years. Sci. Tot. Environ. 265: 27–38.Google Scholar
  28. Milne R. and Brown T.A. 1997. Carbon in the vegetation and soils of Great Britain. J. Environ. Manage. 49: 413–433.Google Scholar
  29. Naden P.S. and McDonald A.T. 1989. Statistical modelling of water colour in the uplands: the upper Nidd catchment 1979–1987. Environ. Pollution 60: 141–163.Google Scholar
  30. Smith T.M. and Shugart H.H. 1993. The potential response of global terrestrial carbon storage in climate change. Water Air and Soil Pollution 70: 629–642.Google Scholar
  31. Swank W.T. 1986. Biological control of solute losses from forest ecosystems. In: Trudgill S.T. (ed.), Solute Processes. John Wiley & Sons, New York, pp. 40–85.Google Scholar
  32. Sykes J.M. and Lane A.M.J. 1996. The United Kingdom Environmental Change Network: Protocols for Standard Measurements of Terrestrial Sites. Natural Environment Research Council, London.Google Scholar
  33. Tans P.P., Fung I.F. and Takahashi T. 1990. Observational constraints the global atmospheric CO2 budget. Science 247: 1431–1437.Google Scholar
  34. Thurman E.M. 1985. Organic Geochemistry of Natural Waters. Nijhoff/Junk, Dordrecht.Google Scholar
  35. Tipping E., Marker A.F.H., Butterwick C., Collett G.D., Cranwell P.A., Ingram J.K.G. et al. 1997. Organic carbon in the Humber Rivers. Sci. Tot. Environ. 194/195: 345–355.Google Scholar
  36. Tipping E., Woof C., Rigg E., Harrison A.F., Ineson P., Taylor K. et al. 1999. Climatic influences on the leaching of dissolved organic matter from upland UK moorland soils, investigated by a field manipulation experiment. Environ. Int. 25: 83–95.Google Scholar
  37. Walling D.E. and Webb B.W. 1985. Estimating the discharge of contaminants to coastal waters by rivers: some cautionary comments. Marine Poll. Bull. 16: 488–492.Google Scholar
  38. Watts C.D., Naden P.S., Machell J. and Banks J. 2001. Long term variation in water colour from Yorkshire catchments. Sci. Tot. Environ. 278: 57–72.Google Scholar
  39. Worrall F., Burt T.P., Jaetan R.Y., Warburton J. and Shedden R. Release of dissolved organic carbon from upland peat. Hydrological Process 16: 3487–3504.Google Scholar

Copyright information

© Kluwer Academic Publishers 2003

Authors and Affiliations

  • Fred Worrall
  • Tim Burt
  • Rosalyn Shedden

There are no affiliations available

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