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Chemistry of Heterocyclic Compounds

, Volume 39, Issue 3, pp 354–356 | Cite as

Nucleophilic Substitution Reactions of 2,4,6-Tris(trinitromethyl)-1,3,5-triazine. 3. Reaction of 2,4,6-Tris(trinitromethyl)-1,3,5-triazine with Azides and Hydrazine

  • A. V. Shastin
  • T. I. Godovikova
  • B. L. Korsunskii
Article

Abstract

As a result of nucleophilic substitution of the trinitromethyl groups in 2,4,6-tris(trinitromethyl)-1,3,5-triazine, the corresponding monoazido and diazido derivatives have been synthesized. The reaction of the starting triazine with hydrazine acetate in the presence of trifluoroacetic acid leads to 1-acetyl-2,2-bis[4,6-bis(trinitromethyl)-1,3,5-triazin-2-yl]hydrazine.

sodium azide hydrazine trimethylsilyl azide 2,4,6-tris(trinitromethyl)-1,3,5-triazine nucleophilic substitution 

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Copyright information

© Plenum Publishing Corporation 2003

Authors and Affiliations

  • A. V. Shastin
    • 1
  • T. I. Godovikova
    • 2
  • B. L. Korsunskii
    • 2
  1. 1.Russian Academy of SciencesInstitute of Problems of Chemical PhysicsMoscow RegionRussia
  2. 2.N. D. Zelinsky Institute of Organic ChemistryMoscowRussia

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