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Journal of Applied Spectroscopy

, Volume 70, Issue 2, pp 216–223 | Cite as

Collisional Depolarization of the Luminescence of Asymmetric Top Molecules in the Gas Phase

  • A. P. Blokhin
  • M. F. Gelin
Article
  • 11 Downloads

Abstract

To describe the collisional depolarization of the luminescence of asymmetric top polyatomic molecules, integral and integrodifferential forms of master equations, in which the effect of collisions is determined by the conditional probabilities of an instantaneous error of rotational phase variables, have been obtained. A symmetry analysis of the master equations has been performed, and it has been shown that in the general case the evolution of optically induced anisotropy is given by five independent relaxation components. The kinetic equations derived are initial equations for specific calculations of the anisotropy relaxation in various collisional models. They make it possible to study the influence of the angular momentum transfer efficiency on the orientational relaxation of anisotropy in a wide range of buffer medium densities: from free rotation to binary collisions in the gas and then to rotational diffusion.

depolarization of fluorescence binary collisions kinetic equations 

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Copyright information

© Plenum Publishing Corporation 2003

Authors and Affiliations

  • A. P. Blokhin
    • 1
  • M. F. Gelin
    • 1
  1. 1.Institute of Molecular and Atomic PhysicsNational Academy of Sciences of BelarusMinskBelarus

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