Journal of Sol-Gel Science and Technology

, Volume 27, Issue 2, pp 157–162 | Cite as

Polymerization Behaviour of Organically Modified Titanium Alkoxides in Solution

  • Uwe Gbureck
  • Jörn Probst
  • Roger Thull
Article

Abstract

Modified titanium alkoxides with polymerizable organic ligands allow the synthesis of copolymers consisting of hybrid organic/inorganic networks. In this work titanium based-precursors were characterized in relation to the polymerization behaviour of the organic matrix. Alkoxide sols were prepared by reaction of methacrylic acid, itaconic acid anhydride, isoeugenol, p-vinylbezoic acid, p-vinylphenylacetic acid, and acetoxyacetomethacrylate with titanium tetraisopropoxide and titanium tetraethoxide. Polymerization reactions were carried out in solution using UV-irradiation and a redox-system of dibenzoylperoxide/N, N-dimethyl-p-toluidine as radical initiators. Especially for chemical activation some complexes showed high reactivity similar to silica-based methacrylates. The systems investigated are capable of acting as adhesive promoters between metal and polymer in dental applications.

titanium alkoxides polymerizable ligands UV-irradiation redox-polymerization FT-Raman spectroscopy 

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Copyright information

© Kluwer Academic Publishers 2003

Authors and Affiliations

  • Uwe Gbureck
    • 1
  • Jörn Probst
    • 1
  • Roger Thull
    • 1
  1. 1.Dept. of Functional Materials in Medicine & Dentistry, ZMK-ClinicUniversity of WurzburgWurzburgGermany

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