Scratch and Abrasion Resistant Coatings on Plastic Lenses—State of the Art, Current Developments and Perspectives

  • G. Schottner
  • K. Rose
  • U. Posset


The manufacturing of ophthalmic lenses is one of the most important markets worldwide and, therefore, strong research efforts are undertaken to continuously improve the quality of the products, either silicate glasses or organic polymer lenses. Hybrid sol-gel based materials play a major role in this highly competitive field and have contributed significantly to the commercial success of the organic base materials. Recent developments concern fast curing and patternable coatings that might soon become part of this business. The compatibility of hybrid sol-gel materials either with organic dyes or with inorganic vacuum borne coatings offers further possibilities to develop highly sophisticated lenses meeting not only customer needs like perfect corrective function, high optical quality and protection, but also high durability as well as cosmetic and decorative aspects. An overview and a few recent developments are outlined below.

abrasion resistance ophthalmic lenses hybrid sol-gel coatings antireflective layer photochromic dyes 


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  1. 1.
    R. Chaffin, Optical World, 8 (1997).Google Scholar
  2. 2.
    R.D. Herold and M.O. Okoroafor, PPG Technology Journal 2, 33 (1996).Google Scholar
  3. 3.
    H. Dislich, Angew. Chem., Int. Ed. Engl. 18, 49 (1979).Google Scholar
  4. 4.
    H.-U. Simmrock, A. Mathy, L. Dominguez, W.H. Meyer, and G. Wegner, Adv. Mater. 101, 1148 (1989).Google Scholar
  5. 5.
    H. Schmidt, B. Seiferling, G. Philipp, and K. Deichmann, in Ultrastructure Processing of Advanced Ceramics, edited by J.D. Mackenzie and D.R. Ulrich (Wiley, Chichester, 1988), p. 651.Google Scholar
  6. 6.
    G. Philipp and H. Schmidt, J. Non-Cryst. Solids 82, 31 (1986).Google Scholar
  7. 7.
    G. Schottner, Chem. Mater. 13, 3422 (2001).Google Scholar
  8. 8.
    B. Lebeau, J. Maquet, C. Sanchez, F. Beaume, and F. Lauprêtre, J. Mater. Chem. 7, 989 (1997).Google Scholar
  9. 9.
    G. Schottner, S. Hofacker, and J. Sandrock, Mat. Res. Soc. Symp. Proc. 519, 251 (1998).Google Scholar
  10. 10.
    B. Riegel, W. Kiefer, S. Hofacker, and G. Schottner, Appl. Spectrosc. 54, 1384 (2000).Google Scholar
  11. 11.
    B. Riegel, W. Kiefer, S. Hofacker, and G. Schottner, J. Sol-Gel Sci. Technol. 24, 139 (2002).Google Scholar
  12. 12.
    M. Templin, U. Wiesner, and H.W. Spiess, Adv. Mater. 9, 814 (1997).Google Scholar
  13. 13.
    G. Medford, J. Pickett, and C. Reynolds, Paint & Coatings Industry XVII, 64 (2001).Google Scholar
  14. 14.
    G. Schottner, J. Kron, K. Rose, and S. Amberg-Schwab, in Matériaux Hybrides, edited by C. Sanchez and F. Babonneau (O.F.T.A., Masson, Paris, 1996), p. 114.Google Scholar
  15. 15.
    H.K. Schmidt, E. Geiter, M. Mennig, H. Krug, C. Becker, and R.-P. Winkler, J. Sol-Gel Sci. Technol. 13, 397 (1998).Google Scholar
  16. 16.
    J.D. Mackenzie and H.P. Bescher, J. Sol-Gel Sci. Technol. 19, 23 (2000).Google Scholar
  17. 17.
    R. Kasemann, H.K. Schmidt, and E. Wintrich, Mater. Res. Soc. Symp. Proc. 346, 915 (1994).Google Scholar
  18. 18.
    T. Iwamoto and J.D. Mackenzie, J. Mater. Sci. 30, 2566 (1995).Google Scholar
  19. 19.
    J.D. Blizzard, P.J. Popa, and J.S. Tonge, in Proc. Silicones in Coatings II (Paint Research Association, Teddington, UK, 1998), p. 46.Google Scholar
  20. 20.
    J. Martínez Urreaga, M.C. Matías, V. Lorenzo, and M.U. de la Orden, Mater. Lett. 45, 293 (2000).Google Scholar
  21. 21.
    M. Witzany, in Thin Films on Glass, edited by H. Bach and D. Krause (Springer, Berlin, 1997), p. 346.Google Scholar
  22. 22.
    J.C. Rostaing and F. Coeret, Thin Solid Films 236, 58 (1993).Google Scholar
  23. 23.
    D. Chen, Solar Energy Mater. & Solar Cells 68, 313 (2001).Google Scholar
  24. 24.
    J.P. Crano, W.S. Kwak, and C.N. Welch, in Applied Photochromic Polymer Systems, edited by C.B. McArdle (Chapman & Hall, New York, 1992), p. 31.Google Scholar
  25. 25.
    B.V. Gemert and D.G. Kish, PPG Technology Journal 5, 53 (1999).Google Scholar
  26. 26.
    W.S. Kwak and J.C. Crano, PPG Technology Journal 2, 45 (1996).Google Scholar
  27. 27.
    M. Mennig, K. Fries, M. Lindenstruth, and H. Schmidt, Thin Solid Films 351, 230 (1999).Google Scholar
  28. 28.
    B. Sahut and P. Roy, Verre 6, 27 (2000).Google Scholar
  29. 29.
    K. Rose, in Organosilicon Chemistry II, edited by N. Auner and J. Weis (VCH, Weinheim, Germany, 1995), p. 649.Google Scholar
  30. 30.
    M. Lüling, Injection Moulding Int., 1998, 41 (1998).Google Scholar
  31. 31.
    H. Dislich, J. Non-Cryst. Solids 57, 371 (1983).Google Scholar
  32. 32.
    A. Gombert, W. Glaubitt, K. Rose, J. Dreibholz, C. Zanke, B. Bläsi, A. Heinzel, W. Horbelt, D. Sporn, W. Döll, V. Wittwer, and J. Luther, Solar Energy 62, 177 (1998).Google Scholar
  33. 33.
    A. Gombert, W. Glaubitt, K. Rose, J. Dreibholz, B. Bläsi, A. Heinzel, D. Sporn, W. Döll, and V. Wittwer, in Proc. 2nd Int. Conf. Coat. Glass (ICCG), edited by H. Pulker, H. Schmidt, and M.A. Aegerter (Elsevier, Amsterdam, 1998).Google Scholar
  34. 34.
    S.J. Wilson and M.C. Hutley, Optica Acta 29, 993 (1982).Google Scholar
  35. 35.
    H.G. Floch and P.F.Belleville, J. Sol-Gel Sci. Technol. 1, 293 (1994).Google Scholar
  36. 36.
    C. Sanchez, B. Lebeau, F. Ribot, and M. In, J. Sol-Gel Sci. Technol. 19, 31 (2000).Google Scholar
  37. 37.
    N. Böhm, A. Materny, W. Kiefer, H. Steins, M.M. Müller, and G. Schottner, Macromolecules 29, 2599 (1996).Google Scholar
  38. 38.
    H. Dürr, Angew. Chem. 101, 427 (1989).Google Scholar
  39. 39.
    L. Hou, H. Schmidt, B. Hoffmann, and M. Mennig, J. Sol-Gel Sci. Technol. 8, 927 (1997).Google Scholar
  40. 40.
    A. Klukowska, U. Posset, G. Schottner, M.L. Wis, C. Salemi-Delvaux, and V. Malatesta, Mater. Sci. 20, 95 (2002).Google Scholar
  41. 41.
    V. Malatesta, in Organic Photochromic and Thermochromic Compounds, vol. 2, edited by J.C. Crano and R. Guglielmetti (Kluwer Academic/Plenum Publishers, New York, 1999), p. 65.Google Scholar

Copyright information

© Kluwer Academic Publishers 2003

Authors and Affiliations

  • G. Schottner
    • 1
  • K. Rose
    • 1
  • U. Posset
    • 1
  1. 1.Fraunhofer-Institut SilicatforschungWürzburgGermany

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