Reaction Kinetics and Catalysis Letters

, Volume 78, Issue 1, pp 59–64 | Cite as

Structure effects of substituents located on the cyclohexene molecular skeleton in catalytic hydrogenations

  • Petr Kačer
  • Leiv Låte
  • Marek Kuzma
  • Libor Červený
Article
  • 31 Downloads

Abstract

Structure effects of various alkylcyclohexenes in heterogeneously catalyzed reactions are discussed. Experimentally evaluated adsorptivity and reactivity were interpreted by means of molecular modelling. Trends in these parameters are correlated with the properties of frontier orbitals.

substituent effects adsorptivity frontier orbitals Competitive hydrogenation 

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Copyright information

© Kluwer Academic Publishers/Akadémiai Kiadó 2003

Authors and Affiliations

  • Petr Kačer
    • 1
  • Leiv Låte
    • 3
  • Marek Kuzma
    • 2
  • Libor Červený
    • 1
  1. 1.Faculty of Chemical TechnologyInstitute of Chemical Technology PraguePrague 6Czech Republic
  2. 2.Institute of MicrobiologyAcademy of Sciences of the Czech RepublicPrague 4Czech Republic
  3. 3.Department of Industrial ChemistryNorwegian University of Science and TechnologyTrondheimNorvay

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