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Russian Journal of Applied Chemistry

, Volume 75, Issue 9, pp 1448–1452 | Cite as

Mechanism of Cyclohexane Ozonolysis Considering Alternative Pathways

  • A. M. Syroezhko
  • V. A. Proskuryakov
  • O. Yu. Begak
Article

Abstract

Ozonolysis of cyclohexane was considered taking into account the alternative pathway of recombination of peroxy radicals to form cyclohexanol and cyclohexanone. The rate constants of the reactions involved were determined experimentally or by calculations (optimization of the process model).

Keywords

Recombination Cyclohexane Alternative Pathway Cyclohexanone Cyclohexanol 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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REFERENCES

  1. 1.
    Syroezhko, A.M., Proskuryakov, V.A., and Begak, O.Yu., Zh. Prikl. Khim., 2002, vol. 75, no. 8, pp. 1320-1328.Google Scholar
  2. 2.
    Maslennikov, S.I., Galimova, L.G., and Komissarov, V.D., Izv. Akad. Nauk SSSR, Ser. Khim., 1979, no. 3, pp. 631-634.Google Scholar
  3. 3.
    Korotkova, N.P., Oxidation of Cyclohexane and Some Oxygen-Containing Compounds with Ozone-Air Mixtures, Cand. Sci. Dissertation, Leningrad, 1978.Google Scholar

Copyright information

© MAIK “Nauka/Interperiodica” 2002

Authors and Affiliations

  • A. M. Syroezhko
    • 1
    • 2
  • V. A. Proskuryakov
    • 1
    • 2
  • O. Yu. Begak
    • 1
    • 2
  1. 1.St. Petersburg State Technological InstituteSt. PetersburgRussia
  2. 2.Federal State Unitary EnterpriseMendeleev Russian Research Institute of MetrologySt. PetersburgRussia

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