Abstract
Freshly deposited stream sediments from six urban centres of the Ganga Plain were collected and analysed for heavy metals to obtain a general scenery of sediment quality. The concentrations of heavy metals varied within a wide range for Cr (115–817), Mn (440–1 750), Fe (28 700–61 100), Co (11.7–29.0), Ni (35–538), Cu (33–1 204), Zn (90–1 974), Pb (14–856) and Cd (0.14–114.8) in mg kg-1. Metal enrichment factors for the stream sediments were <1.5 for Mn, Fe and Co; 1.5–4.1 for Cr, Ni, Cu, Zn and Pb; and 34 for Cd. The anthropogenic source in metals concentrations contributes to 59% Cr, 49% Cu, 52% Zn, 51% Pb and 77% Cd. High positive correlation between concentrations of Cr/Ni, Cr/Cu, Cr/Zn, Ni/Zn, Ni/Cu, Cu/Zn, Cu/Cd, Cu/Pb, Fe/Co, Mn/Co, Zn/Cd, Zn/Pb and Cd/Pb indicate either their common urban origin or their common sink in the stream sediments. The binding capacity of selected metals to sediment carbon and sulphur decreases in order of Zn > Cu > Cr > Ni and Cu > Zn > Cr > Ni, respectively. Stream sediments from Lucknow, Kanpur, Delhi and Agra urban centres have been classified by the proposed Sediment Pollution Index as highly polluted to dangerous sediments. Heavy metal analysis in the <20-μm-fraction of stream sediments appears to be an adequate method for the environmental assessment of urbanisation activities on alluvial rivers. The present study reveals that urban centres act as sources of Cr, Ni, Cu, Zn, Pb and Cd and cause metallic sediment pollution in rivers of the Ganga Plain.
Similar content being viewed by others
References
Ackermann, F.: 1980, ‘A Procedure for Correcting the Grain Size Effect in Heavy Metal Analysis of Esturine and Coastal Sediments’, Environ. Technol. Lett. 1, 518–527.
Ajmal, M., Khan, M. A. and Nomani, A. A.: 1985a, ‘Distribution of Heavy Metals in Water and Sediments of Selected Sites of Yamuna River (India)’, Environ. Mont. Assess. 5, 205–214.
Ajmal, M., Khan, M. A. and Nomani, A. A.: 1985b, ‘Distribution of Heavy Metals in Plants and Fishes of Yamuna River (India)’, Environ. Mont. Assess. 5, 361–367.
Ajmal, M., Khan, M. A. and Nomani, A. A.: 1987, ‘Monitoring of Heavy Metals in the Water and Sediments of the Ganga River, India’, Wat. Sci. Tech. 19(9), 107–117.
Ansari, A. A., Singh, I. B. and Tobschall, H. J.: 2000, ‘Role of Monsoon Rain on Concentrations and Dispersion Patterns of Metal Pollutants in Sediments and Soils of the Ganga Plain, India’, Environ. Geol. 39(3-4), 221–237.
Davies, J. A.: 1984, ‘Complexation of Trace Metals by Adsorbed Natural Organic Matter’, Geochim. Cosmochim. Acta 48, 679–691.
Förstner, U. and Müller, G.: 1981, ‘Concentration of Heavy Metals and Polycyclic Aromatic Hydrocarbons in River Sediments: Geochemical Background, Man's Influence and Environmental Impact’, Geo. Journal 55, 417–432.
Förstner, U. and Wittmann, G. T. W.: 1983, Metal Pollution in the Aquatic Environment, Springer-Verlag, Berlin, Heidelberg, New York, 481 pp.
Hellmann, H.: 1983, ‘Korngrößenverteilung und Organische Spurenstoffe in Gewässersedimenten und Böden’, Fresenius Z. Anal. Chem. 316, 286–289.
Horowitz, A. J.: 1991, A Primer in Sediment-Trace Element Chemistry, Lewis, Chelesea, MI, U.S.A., 136 pp.
Jackwerth, E. and Würfels, M.: 1994, ‘Der Druckaufschluß - Apparative Möglichkeiten, Probleme und Anwendungen’, in M. Stoeppler (ed.), Probennahme und Aufschluß, Springer-Verlag, Berlin, pp. 121–138.
Jha, P. K., Subramanian, V., Sitasawad, R. and Van Grieken, R.: 1990, ‘Heavy Metals in Sediments of the Yamuna River (A Tributary of the Ganges), India’, Sci. Total Environ. 95, 7–27.
Mehra, A., Farago, M. E. and Banerjee, D. K.: 2000, ‘A Study of Eichhornia Crassipes Growing in the Overbank and Floodplain Soils of the River Yamuna in Delhi, India’, Environ. Mont. Assess. 60, 25–45.
Müller, G. Irion, G. and Forstner, U.: 1972, ‘Formation and Diagenesis of Inorganic Ca-Mg Carbonates in the Lacustrine Environment’, Naturwissenschaften 59, 158–164.
Müller, G.: 1979, ‘Schwermetalle in den Sedimenten des Rheins - Veranderungen seit 1971’, Umschau 79(24), 778–783.
Pachauri, R. K. and Sridharan, P. V. (eds): 1998, Looking Back to Think Ahead: Green India 2047, Tata Energy Research Institute, New Delhi, 346 pp.
UNESCO: 1995, A Global Geochemical Database for Environmental and Resource Management, Paris, 122 pp.
Ruppert, H.: 1987, ‘Bestimmung von Schwermetallen im Boden Sowie die ihr Verhalten Bee-influssenden Bodeneigenschaften’, Bayerisches Geologisches Landesamt, Beilage zum GLA-Fachbericht 2, 1–11.
Ramachandran, R.: 1989, Urbanisation and Urban Systems in India, Oxford University Press, Delhi, 364 pp.
Salomons, M.: 1980, ‘Biochemical Processes Affecting Metal Concentrations in Lake Sediments (IJsselmeer, The Netherlands)’, Sci. Total Environ. 16, 217–229.
Singh, M.: 1996, The Ganga River: Fluvial Geomorphology, Sedimentation Processes and Geochemical Studies, Vol. 8, Beiträge zur Umwelt-Geologie Heidelberg, Heidelberg, 141 pp.
Singh, M., Ansari, A. A., Müller, G. and Singh, I. B.: 1997a, ‘Heavy Metals in Freshly Deposited Sediments of the Gomati River (A Tributary of the Ganga River): Effects of Human Activities’, Environ. Geol. 29(3/4), 246–252.
Singh, M.: 2001, ‘Heavy Metal Pollution in Freshly Deposited Sediments of the Yamuna River (The Ganges River Tributary): A Case Study from Delhi and Agra Urban Centres, India’, Environ. Geol. 40(6), 664–671.
Singh, M., Müller, G. and Singh, I. B.: 2002, ‘Baseline Concentrations and Natural Distributions of Heavy Metals in Sediments of the Ganga River, India’, J. Geochem. Exploration, (in review).
Singh, N., Pandey, J., Yunus, M. and Ahmad, K. J.: 1997b, ‘Atmospheric Lead Pollution from Vehicular Emissions-Measurements in Plants, Soil and Milk Samples’, Environ. Monit. Assess. 45, 9–19.
Soares, H. M. V. M., Boaventura, R. A. R., Machado, A. A. S. C. and Silva, J. C. G. E.: 1999, ‘Sediments as Monitors of Heavy Metal Contamination in the Ave River Basin (Portugal): Multivariate Analysis of Data’, Environ. Pollut. 105, 311–323.
Subramanian, V. and Sitasawad, N.: 1984, ‘A Study on Water Quality in the River Yamuna Around Delhi, India’, Water Qual. Bull. 9, 219–222.
Subramanian, V., Van Grieken, R. and Van’t Dack, L.: 1987a, ‘Heavy Metals Distribution in the Sediments of Ganges and Brahmaputra Rivers’, Environ. Geol. Water Sci. 9, 93–103.
Subramanian, V., Sitasawad, N., Abbas, N. and Jha, P. K.: 1987b, ‘Environmental Geology of the Ganga River Basin’, Geol. Soc. of India 30, 335–355.
Tomlinson, D. C., Wilson, J. G., Harris, C. R. and Jeffrey, D. W.: 1980, ‘Problems in the Assessment of Heavy Metal Levels in Estuaries and the Formation of a Pollution Index’, Helgel Meeresuntters 33, 566–575.
Turekian, K. K. and Wedepohl, K. H.: 1961, ‘Distribution of Elements in Some Major Units of the Earth's Crust’, Bull. Geol. Soc. Am. 72, 175–192.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Singh, M., Müller, G. & Singh, I.B. Heavy Metals in Freshly Deposited Stream Sediments of Rivers Associated with Urbanisation of the Ganga Plain, India. Water, Air, & Soil Pollution 141, 35–54 (2002). https://doi.org/10.1023/A:1021339917643
Issue Date:
DOI: https://doi.org/10.1023/A:1021339917643