Russian Chemical Bulletin

, Volume 51, Issue 10, pp 1915–1918

Synthesis and crystal structure of the nanosized supramolecular SmIII complex with macrocyclic cavitand cucurbituril {[Sm(H2O)4]2(C36H36N24O12)3}Br6·44H2O

  • D. G. Samsonenko
  • O. A. Gerasko
  • J. Lipkowski
  • A. V. Virovets
  • V. P. Fedin
Article

DOI: 10.1023/A:1021316921801

Cite this article as:
Samsonenko, D.G., Gerasko, O.A., Lipkowski, J. et al. Russian Chemical Bulletin (2002) 51: 1915. doi:10.1023/A:1021316921801

Abstract

The supramolecular compound {[Sm(H2O)4]2(Cuc)3}Br6·44H2O (Cuc = C36H36N24O12) was synthesized. Its crystal and molecular structure was established by X-ray diffraction analysis. The binuclear complex cation {(Cuc)[Sm(H2O)4](Cuc)[Sm(H2O)4](Cuc)}6+ built from the alternating cucurbituril molecules (C36H36N24O12) and the [Sm(H2O)4]3+ aqua ions is a triple-decker nanosized (33 Å) sandwich.

samarium aqua complex cucurbituril supramolecular compound crystal structure X-ray diffraction analysis 

Copyright information

© Plenum Publishing Corporation 2002

Authors and Affiliations

  • D. G. Samsonenko
    • 1
  • O. A. Gerasko
    • 1
  • J. Lipkowski
    • 2
  • A. V. Virovets
    • 3
  • V. P. Fedin
    • 1
  1. 1.Siberian Branch of the Russian Academy of SciencesInstitute of Inorganic ChemistryNovosibirskRussian Federation
  2. 2.Russian Academy of SciencesG. A. Razuvaev Institute of Organometallic ChemistryNizhny NovgorodRussian Federation
  3. 3.Polish Academy of SciencesInstitute of Physical ChemistryWarsawPoland

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