Frontal Polymerization of Metal-Containing Monomers: A Topical Review

  • Gulzhian I. Dzhardimalieva
  • Anatolii D. Pomogailo
  • Vitaly A. Volpert
Article

Abstract

The peculiarities of the frontal polymerization of metal-containing monomers containing acrylamide (AAm) complexes of transition metal nitrates, M(AAm) x (H2O) y (NO3)2 (M=Co, Ni, Fe, Cu, Zn, Cd, Ba), that are thermally initiated at 353–433 K are considered. It was found that nitrogen oxides (e.g., NO2, NO, N2O), which were formed by partial oxidation of the nitrate groups, were able to initiate the polymerization reaction. The reaction front and a self-sustained thermal wave were determined by structural-chemical and energy factors. The application of a self-propagating frontal polymerization to synthesize metal-containing copolymers was demonstrated. The constants of reactivity of the monomers (r1=0.63, r2=0.70) confirmed the statistical character of the copolymers obtained. Frontal polymerization of the AAm complexes that were filled by silica or glass powder was studied. Adding fillers stabilized the front and resulted in spatially uniform products. By following the controlled thermolysis of the metallopolymer or the controlled change of frontal polymerization into the burning regime lead to the formation of metallopolymer nanocomposites. The products were metal (or metal oxides) nano-scale particles that were stabilized by the polymer matrix that is formed.

frontal polymerization metallopolymer metal-containing monomer acrylamide complexes nanocomposites self-propagating front 

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REFERENCES

  1. 1.
    E. I. Maximov, Dokl. Akad. Nauk SSSR (Dokl. Chem., Engl. Transl.) 19, 1091 (1970).Google Scholar
  2. 2.
    N. M. Chechilo, R. J. Khvilivitskii, and N. S. Enikolopyan, Dokl. Akad. Nauk SSSR (Dokl. Chem., Engl. Transl.) 204, 1180 (1972).Google Scholar
  3. 3.
    J. A. Pojman, J. Willis, D. Fortenberry, V. M. Ilyashenko, and A. M. Khan, J. Polym. Sci. Part A: Polym. Chem. 33, 643 (1995).Google Scholar
  4. 4.
    J. A. Pojman, V. M. Ilyashenko, and A. M. Khan, J. Chem. Soc., Faraday Trans. 92, 2825 (1996).Google Scholar
  5. 5.
    K. G. Kostarev, T. M. Yudina, and S. N. Lysenko, Vysokomol. Soedin. (Polym. Sci., Engl. Transl.) 40, 1896 (1998)Google Scholar
  6. 6.
    P. M. Goldfeder and V. A. Volpert, Math. Problems in Engin. 5, 139 (1999).Google Scholar
  7. 7.
    P. M. Goldfeder, V. A. Volpert, V. M. Ilyashenko, A. M. Khan, J. A. Pojman, and S. E. Solovyev, J. Phys. Chem. B 101, 3474 (1997).Google Scholar
  8. 8.
    S. P. Davtyan, P. V. Zhirkov, and S. A. Vol'fson, Russ. Chem. Rev. 53, 150 (1984).Google Scholar
  9. 9.
    A. Tredici, R. Pecchini, and M. Morbidelli, J. Polym. Sci. Part A: Polym. Chem. 36, 1117 (1998).Google Scholar
  10. 10.
    G. G. Aleksenyan, X. A. Arutyunyan, V. L. Bodneva, S. P. Davtyan, E. V. Prut, B. A. Rozenberg, K. G. Shkadinskii, and N. S. Enikolopyan, Vysokomol. Soedin. (Polym. Sci., Engl. Transl.) 17, 913 (1975)Google Scholar
  11. 11.
    D. Fortenberry and J. A. Pojman, J. Polym. Sci. Part A: Polym. Chem. 38, 1129 (2000).Google Scholar
  12. 12.
    J. A. Pojman, D. I. Fortenberry, and V. M. Ilyashenko, Intern. J. Self-Propagating High-Temperature Synthesis 6, 355 (1997).Google Scholar
  13. 13.
    B. S. Savostyanov, A. D. Pomogailo, S. P. Davtyan, and D. A. Kritskaya, in Tezisy dokl. XIV Chygaevskogo soveshch. po khimii kompl. soedin. (Abstracts of Reports of the XIV Chugaev Meeting on Chemistry of Complexes) (Ivanovo, 1981), Pt. 1, p. 126.Google Scholar
  14. 14.
    A. D. Pomogailo, S. P. Davtyan, A. A. Tomchak, and G. I. Dzhardimalieva, in Materials VIII Vsesoyuzn. Symp. po goreniyu i vzryvu. Kinetika i gorenie (VIII All-Union Symposium on Combustion and Explosion. Kinetics and Combustion) (Chernogolovka, 1986), 8.Google Scholar
  15. 15.
    A. D. Pomogailo and V. S. Savostyanov, Synthesis and Polymerization of Metal-containing Monomers (CRC, Boca Raton, FL, 1994).Google Scholar
  16. 16.
    V. S. Savostyanov, V. I. Ponomarev, A. D. Pomogailo, B. S. Selenova, I. N. Ivleva, A. G. Starikov, and L. O. Atovmyan, Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.) 39, 674 (1990).Google Scholar
  17. 17.
    S. I. Evstratova, G. V. Shilov, G. I. Dzhardimalieva, I. E. Uflyand, A. D. Pomogailo, and S. M. Aldoshin, Koordin. Khimiya (Coord. Chem., Engl. Transl.) 27, 778 (2001).Google Scholar
  18. 18.
    S. I. Evstratova, L. A. Petrova, G. I. Dzhardimalieva, I. E. Uflyand, and A. D. Pomogailo, Zh. Neorgan. Khimii (J. Inorg. Chem., Engl. Transl.) 47, 1344 (2002).Google Scholar
  19. 19.
    H. Irving and J. Williams, J. Chem. Soc. 10, 3192 (1953).Google Scholar
  20. 20.
    V. S. Savostyanov, A. D. Pomogailo, B. S. Selenova, D. A. Kritskaya, and A. N. Ponomarev, Bull. Acad. Sci. USSR, Div. Chem. Sci., (Engl. Transl.) 39, 680 (1990).Google Scholar
  21. 21.
    V. S. Savostyanov, D. A. Kritskaya, A. N. Ponomarev, and A. D. Pomogailo, J. Polym. Sci.: Part A: Polym. Chem. 32, 1201 (1994).Google Scholar
  22. 22.
    V. V. Barelko, A. D. Pomogailo, G. I. Dzhardimalieva, S. I. Evstratova, A. S. Rozenberg, and I. E. Uflyand, Chaos 9, 342 (1999).Google Scholar
  23. 23.
    V. V. Barelko, A. D. Pomogailo, G. I. Dzhardimalieva, S. I. TEvstratova, and A. S. Rozenberg, Dokl. Akad. Nauk (Dokl. Chem., Engl. Transl.) 365, 201 (1999).Google Scholar
  24. 24.
    S. I. Evstratova, B. M. Zuev, G. I. Dzhardimalieva, I. E. Uflyand, and A. D. Pomogailo, Abstr. 218th ACS National Meeting (New Orleans, August 22–26, 1999).Google Scholar
  25. 25.
    N. M. Chechilo and N. S. Enikolopyan, Dokl. Akad. Nauk SSSR (Dokl. Chem., Engl. Transl.) 260, 160 (1976).Google Scholar
  26. 26.
    J. A. Pojman, G. Gunn, C. Patterson, J. Owens, and C. Simmons, J. Phys. Chem. 102, 3927 (1998).Google Scholar
  27. 27.
    K. S. Galyagin and E. I. Vakhrameev, Plast. Massy (Polymers, Engl. Transl.) 36 (1997).Google Scholar
  28. 28.
    M. K. Mishra and S. N. Bhaduri, Appl. Polym. Sci. 30, 723 (1985).Google Scholar
  29. 29.
    V. I. Kurlyankina, I. L. Ushakova, V. A. Molotkov, and A. G. Boldyrev, Zh. Obsh. Khimii (J. General Chem., Engl. Transl.) 69, 97 (1999).Google Scholar
  30. 30.
    S. Masuda, K. Minagawa, S. Yokotani, and M. Tanaka, Europ. Polym. J. 35, 601 (1999).Google Scholar
  31. 31.
    S. P. Davtyan, Khim. Zh. Armeniya (Chem. J. Armenia) 52, 72 (1999).Google Scholar
  32. 32.
    J. Pojman, V. Volpert, and V. A. Volpert, Nonlinear dynamics of SHS-like process in polymer chemistry, in Self-Propagating High-Temperature Synthesis of Materials, A. A. Borisov, L. T. De Luca, and A. G. Merzhanov, eds. (Taylor & Francis, 2002). 20 Dzhardimalieva, Pomogailo, and Volpert Google Scholar
  33. 33.
    M. Fineman and S. D. Ross, J. Polym. Sci 5, 269 (1950).Google Scholar
  34. 34.
    J. P. Kennedy, T. Kelen, and F. Tudos, J. Polym. Sci.: Polym. Chem. Ed. 13, 2277 (1975).Google Scholar
  35. 35.
    C. Erbil, S. Ozdemir, and N. Uyanik, Polymer 41, 1391 (2000).Google Scholar
  36. 36.
    A. S. Rozenberg, A. V. Raevskii, E. I. Aleksandrova, O. I. Kolesova, G. I. Dzhardimalieva, and A. D. Pomogailo, Russ. Chem. Bull., Int. Ed. 50, 901 (2001). Frontal Polymerization of Metal-Containing Monomers: A Topical Review 21 Google Scholar

Copyright information

© Plenum Publishing Corporation 2002

Authors and Affiliations

  • Gulzhian I. Dzhardimalieva
    • 1
  • Anatolii D. Pomogailo
    • 1
  • Vitaly A. Volpert
    • 2
  1. 1.Institute of Problems of Chemical PhysicsRussian Academy of SciencesChernogolovkaRussia
  2. 2.Analyse NumeruiqueUniversite Lyon 1, UMR 5585 CNRSVilleurbanne cedexFrance

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