Journal of Sol-Gel Science and Technology

, Volume 26, Issue 1–3, pp 303–306 | Cite as

Basic Catalyzed Synthesis of Hybrid Sol-Gel Materials Based on 3-Glycidoxypropyltrimethoxysilane

  • Giovanna Brusatin
  • Plinio Innocenzi
  • Massimo Guglielmi
  • Florence Babonneau

Abstract

Hybrid organic-inorganic materials derived from 3-glycidoxypropyltrimethoxysilane have been synthesised using 3-aminoethylaminopropyltriethoxysilane as basic catalyst of epoxy polymerisation and modifier of the structure.

Different amounts of aminoethylaminopropyltriethoxysilane have been used to prepare films and bulk samples, from 17 to 48 mol% with respect to the alkoxide content. The materials have been characterised by Fourier Transform Infrared, Raman and multinuclear solid-state Nuclear Magnetic Resonance spectroscopy.

Complete opening of epoxy rings in 3-glycidoxypropyltrimethoxysilane has been obtained and the different amounts of catalysts employed directly affected the degree of inorganic cross-linking.

hybrid sol-gel glycidoxypropyltrimethoxysilane aminoethylaminopropyltriethoxysilane basic catalysis 

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References

  1. 1.
    H. Schmidt, J. Non-Cryst. Solids 73, 681 (1985).Google Scholar
  2. 2.
    G. Philipp and H. Schmidt, J. Non-Cryst. Solids 82, 31 (1986).Google Scholar
  3. 3.
    H. Schmidt, J. Non-Cryst. Solids 112, 419 (1989).Google Scholar
  4. 4.
    R. Nass, E. Arpac, W. Glaubitt, and H. Schmidt, J. Non-Cryst. Solids 121, 370 (1990).Google Scholar
  5. 5.
    H. Schmidt, J.Non-Cryst.Solids 178, 302 (1994).Google Scholar
  6. 6.
    R. Kasemann, S. Bruck, and H. Schmidt, SPIE 2288, 321 (1994).Google Scholar
  7. 7.
    M. Popall and H. Durand, Electrochim. Acta 37, 1593 (1992).Google Scholar
  8. 8.
    B. Riegel, S. Blittersdorf, W. Kiefer, S. Hofacker, M. Muller, and G. Schottner, J. Non-Cryst. Solids 226, 76 (1998).Google Scholar
  9. 9.
    R. Kasemann and H. Schmidt, in Proc. First EuropeanWorkshop on Hybrid Organic-Inorganic Materials, edited by C. Sanchez and F. Ribot (Chateau de Bierville, France, 1993), p. 171.Google Scholar
  10. 10.
    P. Innocenzi, G. Brusatin, and F. Babonneau, Chem. Mater. 12, 3726 (2000).Google Scholar
  11. 11.
    P. Innocenzi, G. Brusatin, M. Guglielmi, and R. Bertani, Chemistry of Materials, 11, 1672 (1999).Google Scholar
  12. 12.
    G. Brusatin, P. Innocenzi, M. Guglielmi, R. Bozio, M. Meneghetti, R. Signorini, M. Maggini, G. Scorrano, and M. Prato, SPIE 3803, 90 (1999).Google Scholar
  13. 13.
    R. Signorini, M. Meneghetti, R. Bozio, M. Maggini, G. Scorrano, M. Prato, G. Brusatin, P. Innocenzi, and M. Guglielmi, Carbon, 38, 1653 (2000).Google Scholar
  14. 14.
    A. Abbotto, G. Pagani, G. Brusatin, P. Innocenzi, M. Guglielmi, M. Meneghetti, R. Signorini, and R. Bozio, SPIE 3803, 18 (1999).Google Scholar
  15. 15.
    G. Brusatin, E. Miorin, P. Innocenzi, A. Abbotto, L. Beverina, G.A. Pagani, M. Casalboni, F. Sarcinelli, and R. Pizzoferrato, Adv. Funct. Mater 2001, submitted.Google Scholar
  16. 16.
    B. Riegel, S. Blittersorf, W. Kiefer, S. Hofacker, M. Muller, and G. Schottner, J. Non-Cryst. Solids 226, 76 (1998).Google Scholar
  17. 17.
    R.M. Almeida and C.G. Pantano, J. Appl. Phys. 68, 4225 (1990).Google Scholar

Copyright information

© Kluwer Academic Publishers 2003

Authors and Affiliations

  • Giovanna Brusatin
  • Plinio Innocenzi
  • Massimo Guglielmi
  • Florence Babonneau

There are no affiliations available

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