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Reaction Kinetics and Catalysis Letters

, Volume 77, Issue 1, pp 197–205 | Cite as

Non-catalytic liquid phase oxidation of alkenes with nitrous oxide. 2. Oxidation of cyclopentene to cyclopentanone

  • Konstantin A. Dubkov
  • Gennady I. Panov
  • Evgeny V. Starokon
  • Valentin N. Parmon
Article

Abstract

A very efficient way of cyclopentanone production via selective liquid phase oxidation of cyclopentene with nitrous oxide is reported. When contacting liquid cyclopentene at high temperature, nitrous oxide is able to interact directly with the C=C double bond of the hydrocarbon and transfer its oxygen to unsaturated carbon atom. The reaction occurs without catalyst with nearly 100% selectivity.

oxidation nitrous oxide cyclopentene Cyclopentanone 

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Copyright information

© Kluwer Academic Publishers/Akadémiai Kiadó 2002

Authors and Affiliations

  • Konstantin A. Dubkov
    • 1
  • Gennady I. Panov
    • 1
  • Evgeny V. Starokon
    • 1
  • Valentin N. Parmon
    • 1
  1. 1.Boreskov Institute of CatalysisNovosibirskRussia

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