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Russian Journal of Organic Chemistry

, Volume 38, Issue 5, pp 636–650 | Cite as

Stereo- and Regioselective Functionalization of Alkynes Catalyzed by Platinum(IV) and Palladium(II) Complexes in the System I--I3--H2O/MeOH

  • V. P. Ananikov
  • S. A. Mitchenko
  • I. P. Beletskaya
Article

Abstract

Activation of the CÍÄC bond in acetylenic hydrocarbons, catalyzed by iodide complexes of platinum(IV), and the subsequent CÄC coupling reaction make it possible to synthesize 1,4-diiodo-substituted dienes with high stereo- and regioselectivity. The reaction involves intermediate formation of bis-σ-vinyl platinum(IV) complexes which can be isolated in the pure state. Under similar conditions palladium(II) complexes catalyze iodine addition to acetylene.

Keywords

Platinum Organic Chemistry Iodine Hydrocarbon Iodide 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© MAIK “Nauka/Interperiodica” 2002

Authors and Affiliations

  • V. P. Ananikov
    • 1
  • S. A. Mitchenko
    • 2
  • I. P. Beletskaya
    • 3
  1. 1.Zelinskii Institute of Organic ChemistryRussian Academy of SciencesMoscowRussia
  2. 2.Nesmeyanov Institute of Organometallic CompoundsRussian Academy of SciencesMoscowRussia
  3. 3.Department of ChemistryMoscow State UniversityVorob'evy gory, MoscowRussia

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