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Chemistry of Heterocyclic Compounds

, Volume 36, Issue 12, pp 1449–1456 | Cite as

Nitration of Benzo Crown Ethers with Potassium Nitrate in Polyphosphoric Acid

  • A. D. Grebenyuk
  • S. A. Andreev
  • I. A. Stempnevskaya
  • M. G. Levkovich
  • A. K. Tashmukhamedova
Article

Abstract

A general method for the nitration of benzo crown ethers with potassium nitrate in polyphosphoric acid has been developed. Mono- and dinitro derivatives of benzo-12-crown-4, benzo-15-crown-5, dibenzo-18-crown-6, and dibenzo-24-crown-8 have been prepared. The role of complex formation in the regioselective tendency for the nitration of dibenzo-18-crown-6 has been demonstrated.

benzo crown ethers potassium nitrate polyphosphoric acid nitration 

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Copyright information

© Plenum Publishing Corporation 2000

Authors and Affiliations

  • A. D. Grebenyuk
    • 1
  • S. A. Andreev
    • 1
  • I. A. Stempnevskaya
    • 1
  • M. G. Levkovich
    • 1
  • A. K. Tashmukhamedova
    • 1
  1. 1.M. Ulugbek Tashkent State UniversityTashkentUzbekistan

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