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Topics in Catalysis

, Volume 15, Issue 2–4, pp 131–137 | Cite as

Synergistic effects in selective oxidation catalysis: does phase cooperation result in site isolation?

  • E. Bordes
Article

Abstract

Considerations about the possible relations between phase cooperation inducing synergistic effects and site isolation providing for selectivity in mild oxidation of hydrocarbons are proposed. Synergistic effects between several phases arise because of the coherence of their interfaces due to a low mismatch between their structural patterns. As outlined in the paper, the enhanced reactivity is encountered not only in catalytic reactions but also in non-catalytic transformations like allotropic transitions, sublimation, etc. The situations providing for site isolation are given: defective structures, doping and supporting effects on bulk and monolayers, encapsulation of active sites in zeolites are reviewed.

synergistic effects coherent interfaces oxidation catalysis site isolation multicomponent catalysts 

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Copyright information

© Plenum Publishing Corporation 2001

Authors and Affiliations

  • E. Bordes
    • 1
  1. 1.Laboratoire de Catalyse, ESA-CNRS 8010USTLVilleneuve d'Ascq CedexFrance

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